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Light penetration in seawater polluted by dispersed oil: results of radiative transfer modelling

机译:分散油污染海水的光渗透:辐射转移建模的结果

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The downwelling light in seawater is shaped by natural seawater constituents as well as by some external substances which can occur locally and temporally. In this study we focused on dispersed oil droplets which can be found in seawater after an oil spill or in the consequence of intensive shipping, oil extraction and transportation. We applied our modified radiative transfer model based on Monte Carlo code to evaluate the magnitude of potential influence of dispersed oil droplets on the downwelling irradiance and the depth of the euphotic zone. Our model was validated on the basis of in situ measurements for natural (unpolluted) seawater in the Southern Baltic Sea, resulting in less than 5% uncertainty. The optical properties of dispersed Petrobaltic crude oil were calculated on the basis of Mie theory and involved into radiative transfer model. We found that the changes in downwelling light caused by dispersed oil depend on several factors such as oil droplet concentration, size distribution, and the penetration depth (i.e. vertical range of oil droplets occurrence below sea surface). Petrobaltic oil droplets of submicron sizes and penetration depth of 5 m showed a potentially detectable reduction in the depth of the euphotic zone of 5.5% at the concentration of only 10 ppb. Micrometer-sized droplets needed 10 times higher concentration to give a similar effect. Our radiative transfer model provided data to analyse and discuss the influence of each factor separately. This study contributes to the understanding of the change in visible light penetration in seawater affected by dispersed oil.
机译:海水中的沉船光由天然海水成分以及一些外部物质形状,可以在本地和时间发生。在这项研究中,我们专注于分散的油滴,可以在漏油后或在密集的航运,石油提取和运输后发现。我们基于Monte Carlo代码应用了修改的辐射传输模型,以评估分散油滴对沉船辐照度的潜在影响和Euphotic区的深度。我们的模型是在南波罗的海南部海水的原位测量的基础上验证,导致不确定性不到5%。分散的紫罗粒原油的光学性质在MIE理论的基础上计算并参与了辐射转移模型。我们发现,由分散油引起的沉船光的变化取决于诸如油滴浓度,尺寸分布和渗透深度(即海面低于海面的油滴垂直范围)的几个因素。亚微米尺寸和渗透深度为5μm的甲基麦特液滴显示出浓度为5.5%的浓度可检测到的5.5%,浓度仅为10 ppb。米尺尺寸的液滴需要10倍浓度浓度以产生类似的效果。我们的辐射转移模型提供了数据来分析和讨论每个因素的影响。该研究有助于了解受分散油影响的海水中可见光渗透的变化。

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