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Synthesis of nanocomposite films based on conjugated oligomer-2D layered MoS 2 as potential candidate for optoelectronic devices

机译:基于共轭的低聚物-2D层MOS的纳米复合膜的合成 2 作为光电器件的潜在候选

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In this investigation, we have analyzed the structural, electrical, and optical behaviors of pure and composite thin films which are obtained from 2D monolayer molybdenum disulfide (MoS2) flakes, conjugated oligomer (CO) 1,4-Bis(9-ethyl-3-carbazo-vinylene)-9,9-dihexyl-fluorene (BECV-DHF), and by combining CO (BECV-DHF) with MoS2in forms of CO/MoS2composites. All the samples are coated on SiO2/Si substrates using the spin coating procedure where a spin-coating solution has been obtained by dispersing CO and MoS2in ethanol or toluene. The structural morphology of MoS2films and CO/MoS2films of various thicknesses are analyzed using field emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM), and profilometer. These experimental results confirm the formation of MoS2layer composite with oligomer nanocrystals. The optical properties of MoS2, CO, and CO/MoS2films showed that the increased film thickness shifted the spectral peaks towards near infrared (NIR) and ultraviolet–visible (UV) regions of the electromagnetic spectrum. Moreover, devices such as solar cells, flexible memory cell and MOSFET were designed. The I-V characteristics of these devices show that CO/MoS2composite films could serve as potential candidates for organic-inorganic nano-electronic device applications.
机译:在该研究中,我们分析了由2D单层钼二硫化物(MOS2)薄膜(缀合的低聚物(CO)1,4-双(9-乙基-3)获得的纯和复合薄膜的结构,电气和光学行为。(9-乙基-3 -Carbazo-乙烯基)-9,9-二己烯 - 芴(BECV-DHF),并通过将CO(BECV-DHF)与MOS2IN形式的CO / MOS2孔料组合。使用旋涂过程涂覆在SiO 2 / Si基材上的所有样品,其中通过分散CO和MOS2乙醇或甲苯获得旋涂溶液。使用现场发射扫描电子显微镜(Fe-SEM),透射电子显微镜(TEM)和轮廓仪分析各种厚度的MOS2FILMS和CO / MOS2FILM的结构形态。这些实验结果证实了与低聚物纳米晶体的MOS2镶嵌复合材料的形成。 MOS2,CO和CO / MOS2FILMS的光学性质表明,增加的膜厚度将光谱峰移位到近红外(NIR)和紫外线可见(UV)区域的电磁谱。此外,设计了诸如太阳能电池,柔性存储器单元和MOSFET的装置。这些器件的I-V特性表明,CO / MOS2COMPOSE薄膜可以作为有机无机纳米电子器件应用的潜在候选。

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