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首页> 外文期刊>Journal of Modern Physics >Frontier Orbitals, Combustion and Redox Transfer from a Fermionic-Bosonic Orbital Perspective
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Frontier Orbitals, Combustion and Redox Transfer from a Fermionic-Bosonic Orbital Perspective

机译：来自Fermionic-Bosonic Orbital Perspitive的前沿轨道，燃烧和氧化还原转移

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Oxygenations are highly exergonic, yet combustion of organic matter is not spontaneous in an atmosphere that is 21% O_(2). Electrons are fermions with a quantum spin number s of 1/2 ħ . An orbital containing a single electron with s = 1/2 is fermionic. Orbitals can contain a maximum of two electrons with antiparallel spins, i.e. , spin magnetic quantum numbers m _( s ) of 1/2 and -1/2. An orbital filled by an electron couple has s = 0 and bosonic character. The multiplicity of a reactant is defined as |2( S )| + 1 where S is the total spin quantum number. The Wigner spin conservation rules state that multiplicity is conserved. The transmission coefficient κ of absolute reaction rate theory also indicates the necessity for spin conservation. Burning is fermionic combustion that occurs when sufficient energy is applied to a bosonic molecule to cause homolytic bond cleavage yielding fermionic products capable of reaction with the bifermionic frontier orbitals of triplet multiplicity O_(2). Neutrophil leucocytes kill microorganisms by bosonic combustion and employ two mechanisms for changing the multiplicity of O_(2) from triplet to singlet. Microorganisms, composed of bosonic singlet multiplicity molecules, do not directly react with bifermionic O_(2), but are highly susceptible to electrophilic attack by bosonic electronically excited singlet molecular oxygen ( ~(1)O_(2) *) ). Hydride ion (H~(-)) transfer is the common mode of cytoplasmic redox metabolism. Bosonic transfer of an orbital electron couple protects from damage by obviating fermionic reaction with bifermionic O_(2). Bosonic coupled electron transfer raises the consideration that quantum tunneling might be involved in facilitating such redox transfer.
机译：氧气高度出汗，有机物质的燃烧在21％O_（2）的气氛中是自发的。电子是带有Quantum旋转数S的离费米为1/2＆amp;＃295; 。含有具有S = 1/2的单个电子的轨道是FEMIONIC。轨道可以含有最多两个具有反平行旋转的电子，即旋转磁量子数M _（s）为1/2和-1/2。由电子夫妇填充的轨道有S = 0和挥霍结构。反应物的多重性定义为| 2（s）| + 1其中s是总旋转量子数。 Wigner旋转保护规则状态是多样性的节约状态。绝对反应速率理论的透射系数κ还表明了旋转保护的必要性。当施加足够的能量时，燃烧是在伴者分子上施加足够的能量以引起均乳粘粘合的产生，得到能够与三重素多种o_（2）的双重前沿轨道反应的Fermionic产物。中性粒细胞白细胞通过旋转燃烧杀死微生物，并采用两种机制来改变从三联网到单线的多重o_（2）的机制。微生物，由孢子态单态分子组成，不直接与BiferMionic O_（2）反应，但是通过孢子电子激发单分子氧（〜（1）O_（2）*）的电泳攻击高度敏感。氢化物离子（H〜（ - ））转移是细胞质氧化还原代谢的常见模式。轨道电子夫妇的孢子转移通过避免与Bifermionic O_（2）的Fermionic反应来保护损伤。旋转耦合电子传递提高了量子隧道可能涉及促进这种氧化还原转移的考虑因素。

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