首页> 外文期刊>Polish journal of chemical technology >Autothermal Reforming of Diesel Oil for PdCeCrFeCu/Al 2O 3-Catalyzed Hydrogen Production
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Autothermal Reforming of Diesel Oil for PdCeCrFeCu/Al 2O 3-Catalyzed Hydrogen Production

机译:PDCECRFECU / AL 2 O 3 -catalyzed氢气产生的自热改性

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To make clear the feasibility and influence factors of diesel fuel autothermal reforming to hydrogen, PdCeCr- FeCu/Al_(2)O_(3)catalyst was prepared by equivalent-volume impregnation method. Experimental facility based on an adiabatic tubular reactor with preheating section was designed and set up, the behaviors of diesel reforming to hydrogen with straight-run diesel as a raw material according to the analysis of the components were studied. Diesel oil reforming over a catalyst for hydrogen production was analyzed using an adiabatic tubular reactor with a preheating section that was designed and built in-house. The operating conditions were optimized. Under the suitable operating conditions, viz., catalyst bed inlet temperature of 700 °C, diesel liquid space velocity of 0.24 h~(?1), water-carbon ratio of 20, and oxygen-carbon ratio of 0.6, the hydrogen yield reached 28.3 (mol/mol).
机译:为了清楚柴油燃料自热改性对氢的可行性和影响因素,通过等同体积浸渍法制备PDCECR-FECU / AL_(2)O_(3)催化剂。 研究并建立了基于绝热管式反应器的实验设施,研究并建立了柴油重整为氢气的行为,以根据组分分析为原料作为原料。 使用绝热管式反应器分析在氢气产生催化剂上的柴油改造,其中绝热管反应器与预热部分进行设计和内部。 操作条件进行了优化。 在合适的操作条件下,催化剂床入口温度为700°C,柴油液空间速度为0.24小时〜(α1),水 - 碳比为20,氧碳比为0.6,氢收率达到氢 28.3(mol / mol)。

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