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Construction of Fe3O4/FeP Binary Composite Catalyst for Degradation of Tetracycline in Wastewater

机译:Fe3O4 / FEP二元复合催化剂的施工废水中四环素降解

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The abuse of antibiotics greatly aggravates water pollution. Tetracycline hydrochloride (TC), has been widely used all over the world as a typical antibiotic. In order to dispose of TC, a series of Fe3O4/FeP composite materials were synthesized with the combination of hydrothermal synthesis and partial phosphating annealing method. Meanwhile, the morphology and structural characteristics were investigated using characterization such as diffraction of X-rays (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), electro-chemical impedance spectroscopy (EIS) etc. The dark adsorption and photocatalytic activity of Fe3O4/FeP were investigated comprehensively to remove the target molecule tetracycline. Results indicated that Fe3O4/FeP catalysts have a superior performance on dark adsorption, and good effect of TC degradation. Among synthesized photocatalysts, Fe3O4/FeP-6 (molar ratios of Fe:P at 1:6) possessed the optimized performance in adsorption capacity and photodegradation efficiency (88%) comparing to the other ratios. Furthermore, the stability and reusability of Fe3O4/FeP-6 ensured the cyclic photocatalysis experiment. This synthesized catalyst has proved its potential application in wastewater treatment.
机译:抗生素的滥用大大加剧了水污染。四环素盐酸盐(TC),已被全世界广泛用于典型的抗生素。为了处理TC,通过水热合成和部分磷化退火方法的组合合成了一系列Fe 3 O 4 / FEP复合材料。同时,使用表征研究了形态和结构特征,例如X射线(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM),电化学阻抗光谱(EIS)等。黑暗吸附和对Fe3O4 / FEP的光催化活性全面研究以除去靶分子四环素。结果表明,Fe3O4 / FEP催化剂对深色吸附性具有卓越的性能,以及TC降解的良好效果。在合成的光催化剂中,FE3O4 / FEP-6(Fe:P的摩尔比为1:6)具有与其他比率相比的吸附能力和光降解效率(88%)的优化性能。此外,Fe3O4 / FEP-6的稳定性和可重用性确保了循环光催化试验。该合成催化剂已证明其在废水处理中的潜在应用。

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