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First Approach to Measure Interfacial Rheology at High-Pressure Conditions by the Oscillating Drop Technique

机译:通过振荡液滴技术测量高压条件下界面流变学的首先方法

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An oscillating drop rheometer capable of operating under conditions of high pressure and high temperature has been built. The oscillating drop mechanism was able to support pressures as high as 1300 bar and successfully performed oscillations at constant pressure. Apparent elastic and viscous complex moduli were measured for a system of CO2 and synthetic seawater containing 100 ppm of a linear alkyl ethoxylate surfactant for different pressures and temperatures. The moduli had strong dependencies on both pressure and temperature. At temperatures of 40 and 80 °C, the apparent elastic modulus passed through a maximum for pressures between 100 and 300 bar. The harmonic distortion of the oscillations was calculated for all measurements, and it was found that drop oscillations below ca. 2.6 μL caused distortions above 10% due to a mechanical backlash of the motor.
机译:建立了能够在高压和高温条件下运行的振荡降流量计。 振荡下降机构能够支撑高达1300巴的压力,并在恒定压力下成功地进行振荡。 测量表观弹性和粘性复合体的二氧化碳系统,其含有100ppm烷基乙氧基化物表面活性剂的CO 2和合成海水,用于不同的压力和温度。 Moduli对压力和温度有很强的依赖性。 在40和80℃的温度下,表观弹性模量通过100至300巴之间的最大压力。 计算所有测量的振荡的谐波失真,发现它下面下降振荡。 2.6μL由于电动机的机械急流引起的失真10%。

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