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首页> 外文期刊>Ecotoxicology and Environmental Safety >Synchronized separation, concentration and determination of trace sulfadiazine and sulfamethazine in food and environment by using polyoxyethylene lauryl ether-salt aqueous two-phase system coupled to high-performance liquid chromatography
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Synchronized separation, concentration and determination of trace sulfadiazine and sulfamethazine in food and environment by using polyoxyethylene lauryl ether-salt aqueous two-phase system coupled to high-performance liquid chromatography

机译：聚氧乙烯月桂基醚-盐水溶液两相系统与高效液相色谱法同步分离，富集和测定食品和环境中痕量磺胺嘧啶和磺胺二甲嘧啶

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摘要

Polyoxyethylene lauryl ether (POELE10)-Na2C4H4O6 aqueous two-phase extraction system (ATPES) is a novel and green pretreatment technique to trace samples. ATPES coupled with high-performance liquid chromatography (HPLC) is used to analyze synchronously sulfadiazine (SDZ) and sulfamethazine (SMT) in animal by-products (i.e., egg and milk) and environmental water sample. It was found that the extraction efficiency (E%) and the enrichment factor (F) of SDZ and SMT were influenced by the types of salts, the concentration of salt, the concentration of POELE10 and the temperature. The orthogonal experimental design (OED) was adopted in the multi-factor experiment to determine the optimized conditions. The final optimal condition was as following: the concentration of POELE10 is 0.027 g mL(-1), the concentration of Na2C4H4O6 is 0.180 g mL(-1) and the temperature is 35 degrees C. This POELE10-Na2C4H4O6 ATPS was applied to separate and enrich SDZ and SMT in real samples (i.e., water, egg and milk) under the optimal conditions, and it was found that the recovery of SDZ and SMT was 96.20-99.52% with RSD of 0.35-3.41%. The limit of detection (LOD) of this method for the SDZ and SMT in spiked samples was 2.52-3.64 pg mL(-1), and the limit of quantitation (LOQ) of this method for the SDZ and SMT in spiked samples was 8.41-12.15 pg mL(-1). (C) 2016 Elsevier Inc. All rights reserved.
机译：聚氧乙烯月桂基醚（POELE10）-Na2C4H4O6水性两相萃取系统（ATPES）是一种新型的绿色预处理技术，用于痕量样品。 ATPES与高效液相色谱（HPLC）结合用于同时分析动物副产品（例如鸡蛋和牛奶）和环境水样品中的磺胺嘧啶（SDZ）和磺胺二甲嘧啶（SMT）。发现SDZ和SMT的萃取效率（E％）和富集因子（F）受盐的种类，盐的浓度，POELE10的浓度和温度的影响。在多因素实验中采用正交实验设计（OED）来确定最佳条件。最终的最佳条件如下：POELE10的浓度为0.027 g mL（-1），Na2C4H4O6的浓度为0.180 g mL（-1），温度为35摄氏度。将此POELE10-Na2C4H4O6 ATPS应用于分离并在最佳条件下在真实样品（即水，蛋和牛奶）中富集SDZ和SMT，发现SDZ和SMT的回收率为96.20-99.52％，RSD为0.35-3.41％。该方法对加标样品中SDZ和SMT的检出限（LOD）为2.52-3.64 pg mL（-1），此方法对加标样品中SDZ和SMT的定量限（LOQ）为8.41 -12.15 pg毫升（-1）。 （C）2016 Elsevier Inc.保留所有权利。

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  • 来源
    《Ecotoxicology and Environmental Safety》 |2016年第11期|105-113|共9页
  • 作者

    Lu Yang; Cong Biao; Tan Zhenjiang; Yan Yongsheng;

  • 作者单位

    Jilin Normal Univ, Lab Funct Mat Phys & Chem, 1301 Haifeng St, Siping 136000, Peoples R China|Jilin Normal Univ, Jilin Key Lab Numer Simulat, 1301 Haifeng St, Siping 136000, Peoples R China|Jilin Normal Univ, Sch Comp Sci, 1301 Haifeng St, Siping 136000, Peoples R China;

    Jilin Normal Univ, Jilin Key Lab Numer Simulat, 1301 Haifeng St, Siping 136000, Peoples R China|Jilin Normal Univ, Sch Comp Sci, 1301 Haifeng St, Siping 136000, Peoples R China;

    Jilin Normal Univ, Jilin Key Lab Numer Simulat, 1301 Haifeng St, Siping 136000, Peoples R China|Jilin Normal Univ, Sch Comp Sci, 1301 Haifeng St, Siping 136000, Peoples R China;

    Jilin Normal Univ, Lab Funct Mat Phys & Chem, 1301 Haifeng St, Siping 136000, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Aqueous two-phase system; Polyoxyethylene lauryl ether; Separation; Sulfadiazine; Sulfamethazine;

    机译：水两相体系;聚氧乙烯月桂醚;分离;磺胺嘧啶;磺胺二甲嘧啶;

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