Otrzymywanie i charakterystyka komponentów ogniwa tlenkowego Ni-YSZ/YSZ/Sr_(0.8)Ce_(0.1)La_(0.1) MnC_(3-δ)-YSZ

DOROTA SZWAGIERCZAK; JAN KULAWIK; BARBARA GR?GER; ZBIGNIEW PRUSZOWSKI

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Otrzymywanie i charakterystyka komponentów ogniwa tlenkowego Ni-YSZ/YSZ/Sr_(0.8)Ce_(0.1)La_(0.1) MnC_(3-δ)-YSZ

机译：Ni-YSZ / YSZ / Sr_（0.8）Ce_（0.1）La_（0.1）MnC_（3-δ）-YSZ氧化物电池组件的制备与表征

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Metod? odlewania folii i jednoetapowego wspótspiekania przygotowano trzy komponenty tlenkowego ogniwa paliwowego - anod? Ni-YSZ-grafit, elektrolit sta?y YSZ i katod? Sr_(0.8)Ce_(0.1)La_(0.1) MnO_(3-δ)-YSZ. Badano w?a?ciwo?ci surowych i spiekanych elektrod, takie jak skurczliwo??, porowato??, re-zystywno?? i wspó?praca z elektrolitem sta?ym. Zastosowano dwie metody otrzymywania materia?u anodowego - mieszanie NiO z ZrO_2 i bezpr?do-w? metalizacj? niklem tlenku cyrkonu. Druga z tych metod prowadzi?a do ni?szej zawarto?ci niklu niezb?dnej do metalicznego przewodzenia anody i lepszej kompatybilno?ci z elektrolitem sta?ym.%Three components of SOFC structures - Ni/YSZ/graphite anode, YSZ solid electrolyte and S_(0.8)Ce_(0.1)La_(0.1) MnO_(3-δ) -YSZ cathode were prepared by tape casting and one-step cofiring. Properties of green and sintered electrodes were investigated, such as shrinkage, porosity, resistivity and compatibility with the solid electrolyte layer. Two routes of the anode powder preparation - NiO mixing with YSZ and electroless nickel coating on zirconia were applied. The second method leads to a lower nickel content necessary for metallic conductivity of the anode and its better compatibility with the solid electrolyte.

机译：方法？三个薄膜浇铸和一级共烧结，三个氧化物燃料电池组件-阳极？ Ni-YSZ-石墨，YSZ固体电解质和阴极Sr_（0.8）Ce_（0.1）La_（0.1）MnO_（3-δ）-ZYS。测试了原始电极和烧结电极的性能，例如收缩率，孔隙率和电阻率。与固体电解质合作。使用两种获得阳极材料的方法-将NiO与ZrO_2和bezpr？Do-w？混合。金属化？镍氧化锆。这些方法中的第二种导致阳极金属导电所必需的镍含量降低，并与固体电解质更好地相容。％SOFC结构的三个成分-Ni / YSZ /石墨阳极，YSZ固体电解质通过流延铸造和一步共烧制备S_（0.8）Ce_（0.1）La_（0.1）MnO_（3-δ）-YSZ阴极。研究了生电极和烧结电极的性能，例如收缩率，孔隙率，电阻率以及与固体电解质层的相容性。采用了两种制备阳极粉末的方法-将NiO与YSZ混合以及在氧化锆上进行化学镀镍。第二种方法导致较低的镍含量，这对于阳极的金属导电性是必需的，并且其与固体电解质的相容性更好。

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来源
《Elektronika》 |2010年第10期|p.15-183|共5页
作者
DOROTA SZWAGIERCZAK; JAN KULAWIK; BARBARA GR?GER; ZBIGNIEW PRUSZOWSKI;
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作者单位

Instytut Technologii Elektronowej, Oddzia? w Krakowie;

rnInstytut Technologii Elektronowej, Oddzia? w Krakowie;

rnInstytut Technologii Elektronowej, Oddzia? w Krakowie;

rnPolitechnika ?l?ska, Instytut Elektroniki, Gliwice;

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正文语种 pol
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关键词
ogniwo tlenkowe; odlewanie folii; wspó?spiekanie; katoda perowskitowa;

机译：氧化电池铝箔铸造;共烧结;钙钛矿阴极;

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机译：La_（0.1）Sr_（0.9）Co_（0.8）Fe_（0.2）O_（3-δ）和La_（0.1）Sr_（0.9）Co_（0.8）Fe_（0.2）O_（3-δ）-Ce_（可逆固体氧化物燃料电池中带有Ce_（0.9）Gd_（0.1）O_2阻挡层的0.9）Gd_（0.1）O_2氧电极
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机译：La_（0.9）Sr_（0.1）Ga_（0.8）Mg_（0.2）O_（3-δ）电解质和La_（0.8）Sr_（0.2）Cr_（0.82）Ru_（0.18）O_（3-δ）电解质中的操作不均匀性-固体氧化物燃料电池Ce_（0.9）Gd_（0.1）O_（2-δ）复合阳极
3. Nonstoichiometric (La_(0.95)Sr_(0.05))_xGa_(0.9)Mg_(0.1)O_(3-δ) electrolytes and Ce_(0.8)Nd_(0.2)O_(1.9)-(La_(0.95)Sr_(0.05))_xGa_(0.9)Mg_(0.1)O_(3-δ) composite electrolytes for solid oxide fuel cells [J] . X.P. Wang, D.F. Zhou, G.C. Yang, International journal of hydrogen energy . 2014,第2期

机译：非化学计量比（La_（0.95）Sr_（0.05））_ xGa_（0.9）Mg_（0.1）O_（3-δ）电解质和Ce_（0.8）Nd_（0.2）O_（1.9）-（La_（0.95）Sr_（0.05））用于固体氧化物燃料电池的_xGa_（0.9）Mg_（0.1）O_（3-δ）复合电解质
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机译：高性能LA_（0.5）（BA_（0.2）SR_（0.2）CA_（0.1））CO_（0.8）FE_（0.2）O_（3-Δ）-BAZR_（0.1）CE_（0.7）Y_（0.1）YB_（0.1用于质子导电固体氧化物燃料电池的O_（3-δ）复合阴极
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机译：超导体的传输和光谱特性 - 铁磁体 - $ La_ {1.9} sr_ {0.1} CuO_4 $的超导体结 - $ La_ {0.67} Ca_ {0.33} mnO_3 $ - $ La_ {1.9} sr_ {0.1} CuO_4 $

Otrzymywanie i charakterystyka komponentów ogniwa tlenkowego Ni-YSZ/YSZ/Sr_(0.8)Ce_(0.1)La_(0.1) MnC_(3-δ)-YSZ

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