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Upgrading biochar from bio-oil distillation residue by adding bituminous coal: Effects of induction conditions on physicochemical properties

机译:通过添加烟煤从生物油蒸馏残渣升级生物炭:诱导条件对理化性质的影响

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摘要

In this study, biochar was produced by co-pyrolysis of bio-oil distillation residue and bituminous coal under different induction temperature and gas flow rate in a tube furnace. Central composite design was introduced to explore the combined effects of experimental conditions on biochar. The physicochemical properties of biochar from different induction conditions were comprehensively evaluated by elemental analysis, Fourier transform infrared spectrometry (FTIR) and Raman spectroscopy based on response surface methodology. The results showed that bituminous coal was beneficial to the increase in biochar yield, whereas temperature had the opposite effect and the effect of gas flow rate was not obvious. Moreover, C/O ratio increased with the increase of pyrolysis temperature and bio-oil distillation residue in feedstocks, while C/H ratio increased only with increasing temperature. Gas flow rate had a more pronounced descent effect on C/H compared with C/O. In addition, induction conditions caused a relative weakening of C=C stretching vibration and the relative enrichment of C-H in biochar. Bituminous coal, temperature and gas flow rate all contributed to the conversion of small aromatic rings of biochar to large aromatic rings during the co-pyrolysis process.
机译:在这项研究中,生物炭是通过在管式炉中在不同的感应温度和气体流速下将生物油蒸馏残渣和烟煤共热解生产的。引入了中央复合设计,以探索实验条件对生物炭的综合影响。基于响应面分析方法,通过元素分析,傅里叶变换红外光谱(FTIR)和拉曼光谱法,对不同诱导条件下生物炭的理化性质进行了综合评价。结果表明,烟煤有利于生物炭产量的提高,而温度则相反,气体流量的影响不明显。此外,C / O比随原料中热解温度和生物油蒸馏残渣的增加而增加,而C / H比仅随温度的增加而增加。与C / O相比,气体流速对C / H的下降影响更为明显。此外,诱导条件导致生物炭中C = C拉伸振动的相对减弱和C-H的相对富集。烟煤,温度和气体流量都有助于在共热解过程中将生物炭的小芳环转化为大芳环。

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