SEPARATE PRODUCTION OF HYDROGEN AND CARBON MONOXIDE BY CARBON DIOXIDE REFORMING REACTION OF METHANE

Osamu TAKAYASU; Fumihisa SATO; Kyoko OTA

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SEPARATE PRODUCTION OF HYDROGEN AND CARBON MONOXIDE BY CARBON DIOXIDE REFORMING REACTION OF METHANE

机译：甲烷的二氧化碳重整反应分别生产氢气和一氧化碳

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First, modeling of the carbon dioxide reforming reaction (CO_2RR) mechanism was carried out by the chemical affinity values of the individual elementary reactions which would be involved in the overall reaction. The chemical affinity values were obtained from a composition of an outlet stream passed through a catalyst bed. The catalysts used were Ni, Ru, Rh, Pd and Pt supported on MgO. As a result, the decomposition of CH_4 to give carbonaceous deposits and H_2 was the slowest step in CO_2RR. Then, a separate production of H_2 and CO over Ni catalysts from an alternate stream of CH_4 and CO_2 was proved by the use of a flow system equipped with two reactors in parallel, two selector valves, and two gas reservoirs. As a result, such mixtures were obtained as H_2(74/100)+CH_4(18/100) and CO(71/100)+CO_2(17/100) when Ni/α-Al_2O_3 was used as a catalyst.

机译：首先，通过单个基本反应的化学亲和力值对二氧化碳重整反应（CO_2RR）机理进行建模，该基本反应将参与整个反应。从通过催化剂床的出口物流的组成获得化学亲和力值。使用的催化剂是负载在MgO上的Ni，Ru，Rh，Pd和Pt。结果，CH_4分解生成碳质沉积物和H_2是CO_2RR中最慢的步骤。然后，通过使用配备有两个并联的反应器，两个选择阀和两个储气罐的流动系统，证明了由CH_4和CO_2的交替物流在Ni催化剂上分别生产H_2和CO的情况。结果，当使用Ni /α-Al_2O_3作为催化剂时，得到的混合物为H_2（74/100）+ CH_4（18/100）和CO（71/100）+ CO_2（17/100）。

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来源
《Energy Conversion & Management》 |1997年第suppla期|p.391-396|共6页
作者
Osamu TAKAYASU; Fumihisa SATO; Kyoko OTA;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类能源与动力工程;
关键词
carbon dioxide reforming reaction; steam reforming reaction; chemical affinity;

机译：二氧化碳重整反应;蒸汽重整反应;化学亲和力;

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1. Manganese promoting effects on the Co-Ce-Zr-O_x nano catalysts for methane dry reforming with carbon dioxide to hydrogen and carbon monoxide [J] . Ning Wang, Wei Chu, Tao Zhang Chemical engineering journal . 2011,第2a3期

机译：锰对Co-Ce-Zr-O_x纳米催化剂的甲烷促进作用，该催化剂用于将二氧化碳甲烷干法重整为氢气和一氧化碳
2. Corrigendum to 'Efficient dry reforming of methane with carbon dioxide reaction on Ni@Y_2O_3 nanofibers anti-carbon deposition catalyst prepared by electrospinning-hydrothermal method' [Int J Hydrogen Energy 45 (2020) 31494-31506] [J] . Xie Yongshuai, Xie Fengqiong, Wang Lin, International journal of hydrogen energy . 2021,第33期

机译：通过电扫管 - 水热法制备的Ni @ Y_2O_3纳米纤维反应的“二氧化碳反应”甲烷高效改性甲烷的勘探。
3. Hydrogen production and carbon sequestration by steam methane reforming and fracking with carbon dioxide [J] . International journal of hydrogen energy . 2020,第16期

机译：蒸汽甲烷重整和二氧化碳压裂法制氢和固碳
4. Spatial and Temporal Patterns of Methane, Carbon Dioxide, Carbon Monoxide, and Ozone in the Denver-Julesburg Basin Across Regions of Various Oil and Gas Production Densities [C] . Joanna Casey, Ashley Collier, Ricardo Piedrahita, Annual conference of the International Society of Exposure Science . 2016

机译：丹佛-朱尔斯堡盆地不同油气生产密度区域甲烷，二氧化碳，一氧化碳和臭氧的时空分布
5. Kinetics and mechanisms of the ligand substitution reactions of cyclopentadienyl M tetracarbonyl, indenyl M tetracarbonyl, M = niobium or tantalum, and molybdenum(2) (carbon monoxide)(6) [mu-eta(5),eta(5)-cyclopentadienylide-carbon alkyl(2)-cyclopentadienylide] with tributylphosphine, triphenylphosphine and triphenylphosphite. Photo-assisted carbonylation of supercritical ethane, ethane and methane in supercritical carbon dioxide by trans-chlorocarbonylbis(trimethylphosphine)rhodium(I). [D] . Lukmanova-Kline, Dinara Maratovna. 2001

机译：动力学和机制的环戊二烯基M四羰基，茚基M四羰基，M =铌或钽和钼（2）（一氧化碳）（6）[mu-eta（5），eta（5）-cyclopentadienylide-碳烷基（2）-环戊二烯基]与三丁基膦，三苯基膦和亚磷酸三苯酯。通过反氯羰基双（三甲基膦）铑（I）在超临界二氧化碳中对超临界乙烷，乙烷和甲烷进行光辅助羰基化。
6. Emission of methane carbon monoxide carbon dioxide and short‐chain hydrocarbons from vegetation foliage under ultraviolet irradiation [O] . WESLEY T. FRASER, EMANUEL BLEI, STEPHEN C. FRY, -1

机译：紫外线照射下植被叶片中甲烷一氧化碳二氧化碳和短链碳氢化合物的排放
7. An investigation of the reactions of carbon dioxide, carbon monoxide, methane, hydrogen, and water over iron, iron carbides, and iron oxides [O] . Sacco Albert 1977

机译：研究二氧化碳，一氧化碳，甲烷，氢气和水对铁，铁碳化物和氧化铁的反应
8. Cluster Based Reaction Probabilities for Boron with Oxygen, Hydrogen, Water, Nitrogen, Nitrous Oxide, Carbon Dioxide, Carbon Monoxide, Methane, Tetrafluoromethane, and Silane. [R] . Hintz, P. A., Ruatta, S. A., Anderson, S. L. 1989

机译：基于聚类的反应概率硼与氧，氢，水，氮，一氧化二氮，二氧化碳，一氧化碳，甲烷，四氟甲烷和硅烷。

SEPARATE PRODUCTION OF HYDROGEN AND CARBON MONOXIDE BY CARBON DIOXIDE REFORMING REACTION OF METHANE

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