METHANOL SYNTHESIS FROM CO_2 AND H_2 OVER A Cu/ZnO-BASED MULTICOMPONENT CATALYST

Masahiro SAITO; Masami TAKEUCHI; Taiki WATANABE

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METHANOL SYNTHESIS FROM CO_2 AND H_2 OVER A Cu/ZnO-BASED MULTICOMPONENT CATALYST

机译：Cu / ZnO基多组分催化剂上由CO_2和H_2合成甲醇

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The optimum operation conditions for preparing a Cu/ZnO-based multicomponent catalyst (Cu/ZnO/ZrO_2/Al_2O_3/Ga_2O_3) by a coprecipitation method were established. The operation conditions for preparing the precipitate rarely affect the activity of the catalyst, whereas thoroughly washing the precipitate with distilled water to remove Na in the catalyst is greatly important for improving the activity of the catalyst. The Cu/ZnO-based multicomponent catalyst prepared under the optimum preparation conditions was highly active and stable for a long period m a continuous methanol synthesis operation at 523 K with a total pressure of 5 MPa.

机译：建立了通过共沉淀法制备Cu / ZnO基多组分催化剂（Cu / ZnO / ZrO_2 / Al_2O_3 / Ga_2O_3）的最佳操作条件。制备沉淀物的操作条件很少影响催化剂的活性，而用蒸馏水彻底洗涤沉淀物以除去催化剂中的Na对于提高催化剂的活性非常重要。在最佳制备条件下制备的Cu / ZnO基多组分催化剂在523 K的连续甲醇合成操作中，总压力为5 MPa时，具有很高的活性和长期稳定性。

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来源
《Energy Conversion & Management》 |1997年第suppla期|p.403-408|共6页
作者
Masahiro SAITO; Masami TAKEUCHI; Taiki WATANABE;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类能源与动力工程;
关键词
CO_2 hydrogenation; methanol synthesis; Cu/ZnO-based multicomponent catalyst;

机译：CO_2加氢甲醇合成Cu / ZnO基多组分催化剂;

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专利

1. Development of Cu/ZnO-Based High Performance Catalysts for Methanol Synthesis by CO_2 Hydrogenation [J] . M. SAITO, T. FUJITANI, I. TAKAHARA, Energy Conversion & Management . 1995,第6a9期

机译：基于Cu / ZnO的高效CO_2加氢合成甲醇催化剂的开发
2. Comment on the "In situ IR studies on the mechanism of methanol synthesis from CO/H_2 and CO_2/H_2 over Cu-ZnO-Al_2O_3 catalyst" by Wang et al [J] . Frederic C. Meunier The Korean journal of chemical engineering . 2011,第7期

机译：Wang等人评论“ Cu-ZnO-Al_2O_3催化剂上原位红外研究CO / H_2和CO_2 / H_2合成甲醇的机理”
3. In situ IR studies on the mechanism of methanol synthesis from CO/H_2 and CO_2/H_2 over Cu-ZnO-Al_2O_3 catalyst [J] . Xiaojuan Wang, rnHaipeng Zhang, rnWei Li The Korean journal of chemical engineering . 2010,第4期

机译：Cu-ZnO-Al_2O_3催化剂上原位红外研究CO / H_2和CO_2 / H_2合成甲醇的机理
4. Improvement of Stability of Cu/ZnO-Based Multicomponet Catalysts For Methanol Synthesis From CO_2 and H_2 [C] . Masahiro SAITO, Jingang WU, Shengcheng LUO, International conference on greenhouse gas control technologies . 1999

机译：从CO_2和H_2的甲醇合成甲醇合成稳定性提高
5. Effects of dopants on the properties of Cu/ZrO2 catalysts for methanol synthesis and steam reforming. [D] . Pokrovski, Konstantin Aleksandrovich. 2006

机译：掺杂剂对用于甲醇合成和蒸汽重整的Cu / ZrO2催化剂性能的影响。
6. Data on TGA of precursors and SEM of reduced Cu/ZnO catalysts co-modified with aluminium and gallium for methanol synthesis [O] . R. Guil-López, N. Mota, J. Llorente, 2019

机译：铝和镓共改性用于甲醇合成的前驱体的TGA数据和经还原的Cu / ZnO催化剂的SEM数据
7. Influence of copper content on structural features and performance of pre-reduced LaMn_(1-x)Cu_xO_3 (0≤x<1) catalysts for methanol synthesis from CO_2/H_2 [O] . 贾立山, 高敬, 方维平, 2010

机译：铜含量对用于CO_2 / H_2合成甲醇的预还原LaMn_（1-x）Cu_xO_3（0≤x<1）催化剂的结构特征和性能的影响

METHANOL SYNTHESIS FROM CO_2 AND H_2 OVER A Cu/ZnO-BASED MULTICOMPONENT CATALYST

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