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Granulation of nano-scale Ni(OH)_2 cathode materials for high power Ni-MH batteries

机译:用于高功率镍氢电池的纳米级Ni(OH)_2正极材料的造粒

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摘要

Nano-scale β-Ni(OH)_2 and Co(OH)_2 were prepared by controlled crystallization, mixed by ball milling and granulated to form about 5 μm spherical grains by spray drying granulation. The granulation significantly enhanced the electrochemical performance of nano-scale Ni(OH)_2, probably because of good size matching between the active material and the electric conductor. The granulated grains of nano-scale Ni(OH)_2 presented high performance at high discharge C-rate, and its specific capacity at 10 C exceeded that of conventional spherical micro-scale Ni(OH)_2 at 3 C. The granulated nano-scale β-Ni(OH)_2 is a promising cathode active material for high power Ni-MH batteries.
机译:通过控制结晶制备纳米级β-Ni(OH)_2和Co(OH)_2,通过球磨混合并通过喷雾干燥制粒法制粒以形成约5μm的球形颗粒。造粒显着增强了纳米级Ni(OH)_2的电化学性能,这可能是由于活性材料和电导体之间的尺寸匹配良好。纳米级Ni(OH)_2颗粒在高放电C速率下表现出较高的性能,其在10 C时的比容量超过了常规球形微级Ni(OH)_2在3 C时的比容量。 β-Ni(OH)_2级是用于高功率Ni-MH电池的有希望的正极活性材料。

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