Hydrate promoting capabilities of some in water soluble and insoluble organics on the formation of methane gas hydrate

M.M.Mooijer-van den Heuvel; M.Reuvers; R.M. de Deugd

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Hydrate promoting capabilities of some in water soluble and insoluble organics on the formation of methane gas hydrate

机译：甲烷和水合物的形成对某些水溶性和不溶性有机物的水合促进作用

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Sodium chloride(NaCl)has a strong pressure enhancing effect on the three-phase equilibrium liquid water-hydrate-vapor(L_w-H-V)in the ternary system water + methane + sodium chloride(H_2O + CH_4 + NaCl). Recently, however, it became apparent that certain in water soluble and insoluble organic components have the opposite effect on the equilibrium pressure of the three-phase equilibrium L_w-H-V. compared to the hydrate equilibrium pressure of the organic free system, Pressure reductions as high as 80/100 have been observed.

机译：氯化钠（NaCl）对三元体系水+甲烷+氯化钠（H_2O + CH_4 + NaCl）中的三相平衡液态水合水蒸气（L_w-H-V）具有很强的增压作用。然而，近来变得显而易见的是，某些水溶性和不溶性有机组分对三相平衡L_w-H-V的平衡压力具有相反的作用。与有机自由体系的水合物平衡压力相比，已观察到压力降低高达80/100。

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《Entropie》 |2000年第225期|p.50-55|共6页
作者
M.M.Mooijer-van den Heuvel; M.Reuvers; R.M. de Deugd;
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原文格式 PDF
正文语种 eng
中图分类热力工程、热机;
关键词
chemical thermodynamics; formation of methane gas hydrate; hydrate promoting capabilities;

机译：化学热力学甲烷水合物的形成;水合促进能力;

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专利

1. Hydrate Formation by Water Spraying in a Methane + Ethane + Propane Gas Mixture: An Attempt at Promoting Hydrate Formation Utilizing Large-Molecule Guest Substances for Structure-H Hydrates [J] . Hideyuki Tsuji, Takehito Kobayashi, Ryo Ohmura, Energy & fuels . 2005,第3期

机译：通过在甲烷+乙烷+丙烷气体混合物中喷水形成水合物：利用大分子客体物质结构H的水合物促进水合物形成的尝试
2. Influence of water-insoluble organic components on the gas hydrate equilibrium conditions of methane [J] . Mooijer-van den Heuvel MM., Arons JD., Peters CJ. Fluid Phase Equilibria . 2000,第1期

机译：水不溶性有机成分对甲烷气体水合物平衡条件的影响
3. Phase Equilibrium and Dissociation Enthalpies for Hydrates of Various Water-Insoluble Organic Promoters with Methane [J] . Qiu-Nan Lv, Xiao-Sen Li, Zhao-Yang Chen Journal of Chemical and Engineering Data: the ACS Journal for Data . 2013,第11期

机译：各种水不溶性有机促进剂与甲烷的水合物的相平衡和解离焓
4. The occurrenece of methane hydrate in ternary and quaternary systems of methane, water, certain organics, and sodium chloride [C] . M.M.Mooijer-van den Heuvel, M.Reuvers, R.M.de Deugd, Conference on Gas Hydrates . -1

机译：甲烷，水，某些有机物和氯化钠的三元和四元体系中甲烷水合物的发生
5. Phase equilibria and solubility measurements of gases in water in the hydrate formation region [D] . Gaudette, Jason 2007

机译：水合物形成区域中气体在水中的相平衡和溶解度测量
6. A Theoretical Study of the Hydration of Methane from the Aqueous Solution to the sI Hydrate-Liquid Water-Gas Coexistence [O] . Daniel Porfirio Luis, Alcione García-González, Humberto Saint-Martin 2016

机译：从水溶液到sI水合物-水煤气共存甲烷水化的理论研究
7. Investigation of Methane Hydrate Formation in a Recirculating Flow Loop: Modeling of the Kinetics and Tests of Efficiency of Chemical Additives on Hydrate Inhibition Étude de la formation de l'hydrate de méthane dans une conduite de recirculation : modélisation de la cinétique et tests d'efficacité d'additifs chimiques inhibiteurs d'hydrates de gaz [O] . Peytavy J. L., Monfort J. P., Gaillard C. 2006

机译：循环流动回路中甲烷水合物形成的研究：化学添加剂动力学和效率试验模拟水合物抑制研究再循环管线中甲烷水合物的形成：动力学模型和功效测试化学添加剂天然气水合物抑制剂

Hydrate promoting capabilities of some in water soluble and insoluble organics on the formation of methane gas hydrate

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