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首页> 外文期刊>Environmental forensics >Source Apportionment of Ambient Volatile Organic Compounds in Bursa, a Heavily Industrialized City in Turkey
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Source Apportionment of Ambient Volatile Organic Compounds in Bursa, a Heavily Industrialized City in Turkey

机译:土耳其重工业化城市布尔萨的挥发性有机物源分配

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Weekly passive sampling campaigns were carried out over two sample periods to measure volatile organic compounds (VOCs) in Bursa, one of the most heavily industrialized cities in Turkey. The measurements, taken at 40 points in October 2005 and 49 points in April 2006, revealed concentrations of 34 VOCs, including aromatics, olefins, paraffin and halogenated compounds; with benzene, toluene, ethylbenzene, and o, m, and p-xylene polymers (BTEX) being the most abundant compounds detected at all sample points. Toluene was the most abundant VOC found at all sites, with a median concentration ranging from 0.99 μg/m~(-3) in background samples to 35.98 μg/m~(-3) at industrial sites, followed by m- and p-xylene and ethylbenzene. High toluene-to-benzene (T/B) ratios (9.6) were observed at industrial sites, whereas the T/B ratios measured in urban areas and at roadside locations were comparable and were higher than in other countries. A principle component analysis (PCA) using a receptor-oriented source apportionment model was applied to the VOC data and extracted four major sources for both the October and April sampling periods. Principle factors accounted for 85% and 74% of the variance in VOC data for the October and April sample periods, respectively. The identified sources of VOCs in Bursa included: 1) vehicular exhaust (gasoline and diesel engine vehicles), 2) industrial emissions, and 3) evaporative emissions. The explained factors indicated that the urban air in Bursa was influenced by both traffic and industrial sources, each of which displayed different levels.
机译:在两个采样期内,每周进行一次被动采样活动,以测量布尔萨(土耳其最工业化的城市之一)中的挥发性有机化合物(VOC)。在2005年10月的40点和2006年4月的49点进行的测量显示34种VOC的浓度,包括芳烃,烯烃,石蜡和卤代化合物;苯,甲苯,乙苯,邻,间和对二甲苯聚合物(BTEX)是在所有采样点检测到的最丰富的化合物。甲苯是所有场所中最丰富的挥发性有机化合物,中位浓度范围从背景样品的0.99μg/ m〜(-3)到工业场所的35.98μg/ m〜(-3),其次是m-和p-二甲苯和乙苯。在工业现场观察到较高的甲苯/苯(T / B)比(9.6),而在城市地区和路边位置测得的T / B比具有可比性,并且高于其他国家。使用面向受体的源分配模型的主成分分析(PCA)应用于VOC数据,并提取了十月和四月采样期间的四个主要来源。在10月和4月采样期间,主要因素分别占VOC数据方差的85%和74%。在布尔萨,已确定的挥发性有机化合物来源包括:1)车辆废气(汽油和柴油发动机车辆),2)工业废气和3)蒸发废气。解释的因素表明,布尔萨的城市空气受到交通和工业来源的影响,每种来源都表现出不同的水平。

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