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High Surface Area Rice Husk-Based Activated Carbon Prepared by Chemical Activation with ZnCl_2-CuCl_2 Composite Activator

机译:ZnCl_2-CuCl_2复合活化剂的化学活化制备高表面积稻壳基活性炭

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摘要

In this study, rice husks (RHs), an agriculture by-product, were used as precursor for the production of activated carbon by chemical activation with ZnCl_2-CuCl_2 composite activator. The effect of process variables, such as ZnCl_2 concentration, CuCl_2 concentration, activation temperature, and activation time, were investigated. The optimal process condition was obtained through orthogonal test. Then the morphology, pore structure, and surface chemistry of rice husk-based activated carbon (RAC) were analyzed. When using 5 mol/L ZnCl_2 and 0.4 mol/L CuCl_2 at the carbonization temperature of 500℃ for 1.5 h, the BET surface area of the produced activated carbon was as high as 1924 m~2/g and the total pole volume reached 1.493 cm~3/g. The surface area was strongly affected by ZnCl_2 concentration and the subsequent activation temperature. RAC prepared under the optimum conditions had remarkable adsorptive properties and notable treatment effect for fuchsine.
机译:在这项研究中,稻壳(RHs)是一种农业副产品,被用作通过ZnCl_2-CuCl_2复合活化剂化学活化生产活性炭的前体。研究了ZnCl_2浓度,CuCl_2浓度,活化温度和活化时间等工艺变量的影响。通过正交试验确定了最佳工艺条件。然后分析了稻壳基活性炭(RAC)的形态,孔结构和表面化学。在500℃的碳化温度下用5 mol / L的ZnCl_2和0.4 mol / L的CuCl_2进行1.5 h时,所制得的活性炭的BET表面积高达1924 m〜2 / g,总极容达到1.493。厘米〜3 /克。表面积受ZnCl_2浓度和随后的活化温度的强烈影响。在最佳条件下制备的RAC具有很好的吸附性能,对品红的处理效果显着。

著录项

  • 来源
    《Environmental progress & sustainable energy》 |2016年第1期|133-140|共8页
  • 作者

    Bin Liu; Jie Gu; Jianbin Zhou;

  • 作者单位

    College of Chemical Engineer, Nanjing Forestry University, Nanjing, Jiang Su 210037, China;

    College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, Jiang Su 210037, China;

    College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, Jiang Su 210037, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    rice husk; activated carbon; characterization; composite activator;

    机译:稻壳;活性炭;表征;复合活化剂;

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