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The potential of microplastics as adsorbents of sodium dodecyl benzene sulfonate and chromium in an aqueous environment

机译:微塑料作为十二烷基苯磺酸钠和水性环境中铬的吸附剂的潜力

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摘要

Considering the omnipresence of microplastics (MPs) in aquatic environments, they are expected to exert sig-nificatn impacts as carriers for diverse waterborne pollutants. In this work, the adsorptive behavior of two ionic components (i.e., sodium dodecyl benzene sulfonate (SDBS) and Cr(Ⅵ)) has been explored against the two types of MPs as model adsorbents, namely poly (ethylene terephthalate) (PET) and polystyrene (PS). The influence of key variables (e.g., pH, particle size, and dose of the MPs) on their adsorption behavior is evaluated from various respects. The maximum adsorption capacity values of SDBS on PET and PS are estimated to be 4.80 and 4.65 mg·g~(-1), respectively, while those of Cr(Ⅵ) ions are significantly lower at 0.080 and 0.072 mg·g~(-1), respectively, The adsorptive equilibrium of SDBS is best described in relation to pH and MP size by a Freundlich isotherm. In contrast, the adsorption behavior of Cr(Ⅵ) is best accounted for by a Langmuir isotherm to indicate its adsorption across at least two active surface sites.
机译:考虑到微型环境中微型塑料(MPS)的无所话,它们预计将施加SIG-NIFICATN作为多元化水性污染物的载体的影响。在这项工作中,已经探讨了两种离子组分的吸附行为(即十二烷基苯磺酸钠(SDB)和Cr(ⅵ))作为模型吸附剂,即聚(乙二醇酯)(PET)和聚苯乙烯(PS)。关键变量(例如,pH,粒度和MPS的剂量)对其吸附行为的影响是从各种方面评估的。 PET和PS上SDBS的最大吸附容量分别估计为4.80和4.65mg·g〜(-1),而Cr(ⅵ)离子的离子在0.080和0.072 mg·g〜( - 1)分别通过Freundlich等温线的pH和MP尺寸可以最佳地描述SDB的吸附平衡。相反,Cr(Ⅵ)的吸附行为最适合于朗米尔等温线,以表明其在至少两个活性表面位点上的吸附。

著录项

  • 来源
    《Environmental research》 |2021年第2期|111057.1-111057.11|共11页
  • 作者单位

    School of Ecology and Environment Science Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China State Key Laboratory of Urban Water Resource and Environment Harbin Institute of Technology Harbin 150001 PR China Zhengzhou Key Laboratory of Water Resource and Environment Zhengzhou 450001 China Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection Zhengzhou 450001 PR China;

    School of Ecology and Environment Science Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China Zhengzhou Key Laboratory of Water Resource and Environment Zhengzhou 450001 China Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection Zhengzhou 450001 PR China;

    School of Ecology and Environment Science Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China Zhengzhou Key Laboratory of Water Resource and Environment Zhengzhou 450001 China Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection Zhengzhou 450001 PR China;

    School of Ecology and Environment Science Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China Zhengzhou Key Laboratory of Water Resource and Environment Zhengzhou 450001 China Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection Zhengzhou 450001 PR China School of Water Conservancy Engineering Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China Yellow River Institute for Ecological Protection and Regional Coordination Development Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China;

    Zhengzhou Key Laboratory of Water Resource and Environment Zhengzhou 450001 China Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection Zhengzhou 450001 PR China School of Water Conservancy Engineering Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China Yellow River Institute for Ecological Protection and Regional Coordination Development Zhengzhou University 100 Kexue Avenue Zhengzhou Henan 450001 PR China;

    Faculty of Science and Technology Bournemouth University Talbot Campus Fern Barrow Poole BH12 5BB United Kingdom;

    Cambridge Graphene Centre Department of Engineering University of Cambridge Cambridge CB3 OFA United Kingdom;

    Center for Environmental and Energy Research (CEER) - Engineering of Materials Via Catalysis and Characterization Ghent University Global Campus 119-5 Songdomunhwa-Ro Yeonsu-Gu Incheon 406-840 South Korea Department of Green Chemistry and Technology Faculty of Bioscience Engineering Ghent University Coupure Links 653 Ghent B-9000 Belgium;

    Department of Civil and Environmental Engineering Hanyang University Seoul 04763 South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Microplastics; SDBS; Cr(Ⅵ); pH; Particle size; Adsorption modeling;

    机译:微塑料;SDBS;Cr(ⅵ);pH;粒径;吸附建模;

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