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首页> 外文期刊>Environmental Science & Technology >Estimation of Exposure to Organic Flame Retardants via Hand Wipe, Surface Wipe, and Dust: Comparability of Different Assessment Strategies
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Estimation of Exposure to Organic Flame Retardants via Hand Wipe, Surface Wipe, and Dust: Comparability of Different Assessment Strategies

机译:通过手擦拭,表面擦拭和灰尘接触有机阻燃剂的估算:不同评估策略的可比性

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摘要

This study aimed to investigate the exposure of three occupational populations (i.e., office worker, taxi drivers, and security guards) to flame retardants by comparing different sampling approaches (i.e., hand wipe, surface wipe, and dust). Hand wipe samples were collected from 68 participants from three populations in Beijing, China. Dust and/or surface wipes were also sampled from their respective occupational workplaces. Ten phosphorus flame retardants (PFRs), two novel brominated flame retardants (NBFRs) and eight polybrominated diphenyl ethers (PBDEs) were analyzed. BDE209, decabromodiphenylethane (DBDPE), tris(chloropropyl) phosphate isomers (Sigma TCPP), tris(2-chloroethyl) phosphate (TCEP) and triphenyl phosphate (TPHP) were detected in at least 95% of the samples, collectively accounting for over 90% of the total concentrations in each type of samples. Concentrations and composition profiles of flame retardants differed in hand wipes of the three populations with summed level of all target compounds (Sigma FRs) ranked as taxi drivers office workers security guards. Most FRs in hand wipes were significantly correlated with those in surface wipes, whereas the correlations between hand wipes and dust are weak. Estimated exposure to FRs via dust ingestion and dermal absorption for each population varied when using different types of samples for exposure assessment, suggesting the importance of sampling strategy selection. Estimation via hand wipes indicated that taxi drivers were subjected to greater exposure to PFRs among three populations, while office workers were subjected to greater BFR exposure. Our data suggest hand wipes have the potential of being standardized into a noninvasive method for evaluating human exposure to environmental contaminants across different populations.
机译:这项研究旨在通过比较不同的采样方法(手擦,表面擦拭和灰尘)来调查三个职业人群(即上班族,出租车司机和保安人员)接触阻燃剂的情况。从中国北京的三个人群的68名参与者中收集了擦手样本。灰尘和/或表面抹布也从其各自的工作场所取样。分析了十种磷阻燃剂(PFR),两种新型溴化阻燃剂(NBFR)和八种多溴联苯醚(PBDEs)。在至少95%的样品中检出了BDE209,十溴二苯乙烷(DBDPE),磷酸三(氯丙基)酯异构体(Sigma TCPP),磷酸三(2-氯乙基)酯(TCEP)和磷酸三苯酯(TPHP),这些样品合计超过90每种样品中总浓度的百分比。三种人群的擦拭巾中阻燃剂的浓度和组成特征有所不同,所有目标化合物(西格玛阻燃剂)的总含量为出租车司机>办公室工作人员>保安人员。擦拭巾中的大多数阻燃剂与表面擦拭剂中的FR显着相关,而擦拭巾与灰尘之间的相关性较弱。当使用不同类型的样本进行暴露评估时,每个人群通过粉尘摄入和皮肤吸收所致的FRs估计暴露量各不相同,这表明选择抽样策略的重要性。通过擦手纸进行的估算表明,出租车司机在三个人群中的PFR暴露量更大,而上班族则对BFR暴露量更大。我们的数据表明,擦手纸有可能被标准化为一种非侵入性的方法,用于评估不同人群的人接触环境污染物的情况。

著录项

  • 来源
    《Environmental Science & Technology》 |2018年第17期|9946-9953|共8页
  • 作者单位

    Tsinghua Univ, Sch Environm, Beijing Key Lab Emerging Organ Contaminants Contr, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China;

    Henan Normal Univ, Sch Environm, Key Lab Yellow River & Huai River Water Environm, Minist Educ,Henan Key Lab Environm Pollut Control, Xinxiang 453007, Peoples R China;

    Tsinghua Univ, Sch Environm, Beijing Key Lab Emerging Organ Contaminants Contr, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China;

    Tsinghua Univ, Sch Environm, Beijing Key Lab Emerging Organ Contaminants Contr, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China;

    Henan Normal Univ, Sch Environm, Key Lab Yellow River & Huai River Water Environm, Minist Educ,Henan Key Lab Environm Pollut Control, Xinxiang 453007, Peoples R China;

    Henan Normal Univ, Sch Environm, Key Lab Yellow River & Huai River Water Environm, Minist Educ,Henan Key Lab Environm Pollut Control, Xinxiang 453007, Peoples R China;

    Tsinghua Univ, Sch Environm, Beijing Key Lab Emerging Organ Contaminants Contr, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China;

    Tsinghua Univ, Sch Environm, Beijing Key Lab Emerging Organ Contaminants Contr, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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