Identification of Mutagenic Aromatic Amines in River Samples with Industrial Wastewater Impact

Melis Muz; Janek Paul Dann; Felix Jaeger; Werner Brack; Martin Krauss

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Identification of Mutagenic Aromatic Amines in River Samples with Industrial Wastewater Impact

机译：工业废水影响下河道样品中致突变性芳香胺的鉴定

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Aromatic amines are one of the most important classes of compounds contributing to surface water mutagenicity due to their widespread occurrence as precursors and transformation products of dyes, pharmaceuticals, agrochemicals, and other compound classes. In this study, we implemented a workflow including novel analytical and data evaluation methods aiming to identify aromatic amines in six mutagenic wastewater effluents from a chemical-industrial area in Germany, collected by the passive sampler Blue Rayon. We identified 14 amines including the two potent mutagenic aromatic amines 2,3- and 2,8-phenazinediamine, which were reported for the first time as environmental contaminants. These two isomers accounted between 4.2 and 86% of the mutagenicity of the blue rayon extracts and may be byproducts of dye production at the studied site.

机译：芳香胺是导致地表水致突变性的最重要的化合物之一，因为它们作为染料，药物，农用化学品和其他化合物的前体和转化产物而广泛存在。在这项研究中，我们实施了包括新颖的分析和数据评估方法在内的工作流程，旨在鉴定无源采样器Blue Rayon收集的来自德国化学工业区的六种诱变废水中的芳香胺。我们鉴定了14种胺，其中包括两种有效的诱变芳香族胺2,3-和2,8-吩嗪二胺，这是首次被报道为环境污染物。这两种异构体占蓝色人造丝提取物诱变性的4.2％至86％，并且可能是研究地点染料生产的副产品。

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《Environmental Science & Technology》 |2017年第8期|4681-4688|共8页
作者
Melis Muz; Janek Paul Dann; Felix Jaeger; Werner Brack; Martin Krauss;
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作者单位

Department Effect-Directed Analysis, Helmholtz Centre for Environmental Research - UFZ, Permoserstrasse 15, 04318 Leipzig, Germany,Department of Ecosystem Analyses, Institute for Environmental Research, RWTH Aachen University, Worringerweg 1, 52074 Aachen, Germany;

Department Effect-Directed Analysis, Helmholtz Centre for Environmental Research - UFZ, Permoserstrasse 15, 04318 Leipzig, Germany;

Synchem UG & Co. KG, Am Kies 2, 34587 Felsberg-Altenburg, Germany;

Department Effect-Directed Analysis, Helmholtz Centre for Environmental Research - UFZ, Permoserstrasse 15, 04318 Leipzig, Germany,Department of Ecosystem Analyses, Institute for Environmental Research, RWTH Aachen University, Worringerweg 1, 52074 Aachen, Germany;

Department Effect-Directed Analysis, Helmholtz Centre for Environmental Research - UFZ, Permoserstrasse 15, 04318 Leipzig, Germany;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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1. Computational identification of structural factors affecting the mutagenic potential of aromatic amines: study design and experimental validation [J] . Slavov Svetoslav H., Stoyanova-Slavova Iva, Mattes William, Archives of Toxicology . 2018,第7期

机译：影响芳香胺诱变潜力的结构因素的计算鉴定：研究设计与实验验证
2. Identification of 2-amino-1,7-dimethylimidazo(4,5-g)quinoxaline: an abundant mutagenic heterocyclic aromatic amine formed in cooked beef. [J] . Turesky RJ, Goodenough AK, Ni W, Chemical research in toxicology . 2007,第3期

机译：鉴定2-氨基-1,7-二甲基咪唑并（4,5-g）喹喔啉：在煮熟的牛肉中形成的大量诱变杂环芳香胺。
3. Identification of mutagenic heterocyclic amines (IQ, Trp-P-1 and AalphaC) in the water of the Danube river. [J] . Kataoka H, Hayatsu T, Hietsch G, Mutation Research: International Journal on Mutagenesis, Chromosome Breakage and Related Subjects . 2000,第1期

机译：多瑙河水中的致突变杂环胺（IQ，Trp-P-1和AalphaC）的鉴定。
4. Environmental impacts of wastewater from low-rank coal handling processes in terms of mutagenicity and acute toxicity [C] . T. Nakajima, K. Kuzumaki, H. Hasegawa, International Conference on the Impact of Environmental Factors on Health; 20070627-29; Malta(MT) . 2007

机译：低阶煤处理工艺对致突变性和急性毒性的环境影响
5. A comparative quantitative structure-activity relationship case study for mutagenic potency on aromatic amines with mechanistic implications. [D] . Sumner, Mitchell Joseph. 2016

机译：一个比较定量的构效关系的案例研究对具有机械意义的芳香胺的致突变力。
6. Identification of 2-Amino-17-dimethylimidazo45-gquinoxaline: An Abundant Mutagenic Heterocyclic Aromatic Amine Formed in Cooked Beef [O] . Robert J. Turesky, Angela K. Goodenough, Weijuan Ni, -1

机译：鉴定2-氨基-17-二甲基咪唑并45-g喹喔啉：煮熟的牛肉中形成的大量致突变杂环芳香胺
7. Identification of Mutagenic Aromatic Amines in River Samples with Industrial Wastewater Impact [O] . -1

机译：具有工业废水影响的河流样本中致突变性芳族胺的鉴定

Identification of Mutagenic Aromatic Amines in River Samples with Industrial Wastewater Impact

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