• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Environmental Science & Technology >Metabolism and Photolysis of 2,4-Dinitroanisole in Arabidopsis
【24h】

Metabolism and Photolysis of 2,4-Dinitroanisole in Arabidopsis

机译：2,4-二硝基苯甲醚在拟南芥中的代谢和光解

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

New insensitive munitions explosives, including 2,4-dinitroanisole (DNAN), are replacing traditional explosive compounds to protect soldiers and simplify transport logistics. Despite the occupational safety benefits of these new explosives, feasible strategies for cleaning up DNAN from soil and water have not been developed. Here, we evaluate the metabolism of DNAN by the model plant Arabidopsis to determine whether phytoremediation can be used to clean up contaminated sites. Furthermore, we evaluate the role of photodegradation of DNAN and its plant metabolites within Arabidopsis leaves to determine the potential impact of photolysis on the phytoremediation of contaminants. When exposed to DNAN for three days, Arabidopsis took up and metabolized 67% of the DNAN in hydroponic solution. We used high resolution and tandem mass spectrometry in combination with stable-isotope labeled DNAN to confirm ten phase II DNAN metabolites in Arabidopsis. The plants separately reduced both the para- and ortho-nitro groups and produced glycosylated products that accumulated within plant tissues. Both DNAN and a glycosylated metabolite were subsequently photolyzed within leaf tissue under simulated sunlight, and [~(15)N_2]DNAN yielded ~(15)NO_2~- in leaves. Therefore, photolysis inside leaves may be an important, yet under-explored, phytoremediation mechanism.
机译：新的不敏感弹药炸药，包括2,4-二硝基苯甲醚（DNAN），正在取代传统的炸药，以保护士兵并简化运输后勤。尽管这些新型炸药具有职业安全优势，但尚未开发出从土壤和水中清除DNAN的可行策略。在这里，我们通过模型植物拟南芥评估DNAN的代谢，以确定是否可以使用植物修复来清理污染的部位。此外，我们评估了拟南芥叶片中DNAN及其植物代谢产物的光降解作用，以确定光解对污染物的植物修复的潜在影响。当暴露于DNAN中三天时，拟南芥吸收并代谢了水培溶液中67％的DNAN。我们将高分辨率和串联质谱与稳定同位素标记的DNAN结合使用，以确认拟南芥中的十种II期DNAN代谢产物。植物分别还原对硝基和邻硝基基团，并产生在植物组织中积累的糖基化产物。随后，DNAN和糖基化代谢物都在模拟阳光下在叶片组织内进行光解，[〜（15）N_2] DNAN在叶片中产生〜（15）NO_2〜-。因此，叶片内部的光解可能是重要的但尚未被充分研究的植物修复机制。

著录项

  • 来源
    《Environmental Science & Technology》 |2017年第23期|13714-13722|共9页
  • 作者

    Hunter W. Schroer; Xueshu Li; Hans-Joachim Lehmler; Craig L. Just;

  • 作者单位

    Civil & Environmental Engineering, The University of Iowa, Iowa City, Iowa 52242, United States;

    Occupational & Environmental Health, The University of Iowa, Iowa City, Iowa 52246, United States;

    Occupational & Environmental Health, The University of Iowa, Iowa City, Iowa 52246, United States;

    Civil & Environmental Engineering, The University of Iowa, Iowa City, Iowa 52242, United States;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号