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首页> 外文期刊>Environmental Science & Technology >From Clothing to Laundry Water: Investigating the Fate of Phthalates, Brominated Flame Retardants, and Organophosphate Esters
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From Clothing to Laundry Water: Investigating the Fate of Phthalates, Brominated Flame Retardants, and Organophosphate Esters

机译：从衣物到洗衣水：研究邻苯二甲酸盐，溴化阻燃剂和有机磷酸酯的命运

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摘要

The accumulation of phthalate esters, brominated flame retardants (BFRs) and organophosphate esters (OPEs) by clothing from indoor air and transfer via laundering to outdoors were investigated. Over 30 days cotton and polyester fabrics accumulated 3475 and 1950 ng/dm~2 Σ_5phthalates, 65 and 78 ng/dm~2 Σ_(10)BFRs, and 1200 and 310 ng/dm~2 Σ_8OPEs, respectively. Planar surface area concentrations of OPEs and low molecular weight phthalates were significantly greater in cotton than polyester and similar for BFRs and high molecular weight phthalates. This difference was significantly and inversely correlated with K_(ow), suggesting greater sorption of polar compounds to polar cotton. Chemical release from cotton and polyester to laundry water was ＞80％ of aliphatic OPEs (log K_(ow) ＜ 4), ＜ 50％ of OPEs with an aromatic structure, 50-100％ of low molecular weight phthalates (log K_(ow) 4-6), and ＜ detection-35％ of higher molecular weight phthalates (log Kow ＞ 8) and BFRs (log K_(ow) ＞ 6). These results support the hypothesis that clothing acts an efficient conveyer of soluble semivolatile organic compounds (SVOCs) from indoors to outdoors through accumulation from air and then release during laundering. Clothes drying could as well contribute to the release of chemicals emitted by electric dryers. The results also have implications for dermal exposure.
机译：研究了衣服从室内空气中积累的邻苯二甲酸酯，溴化阻燃剂（BFRs）和有机磷酸酯（OPEs）以及通过洗涤转移到室外的过程。在30天内，棉和涤纶织物分别累积了3475和1950 ng / dm〜2Σ_5邻苯二甲酸酯，65和78 ng / dm〜2Σ_（10）BFR，1200和310 ng / dm〜2Σ_8OPEs。棉中的OPEs和低分子量邻苯二甲酸酯的平面表面积浓度显着大于聚酯，而BFR和高分子量邻苯二甲酸酯的平面表面积浓度相近。这种差异与K_（ow）显着且呈负相关，表明极性化合物对极性棉的吸附更大。从棉和聚酯到衣物水中的化学释放量是脂肪族OPE的> 80％（log K_（ow）＜4），芳香结构的OPEs ＜50％，低分子量邻苯二甲酸酯的50-100％（log K_（ow） ）4-6），和<检测-35％的高分子量邻苯二甲酸酯（log Kow＞ 8）和BFRs（log K_（ow）＞ 6）。这些结果支持以下假设：衣物通过空气中的积聚作用，从室内到室外有效地输送可溶性半挥发性有机化合物（SVOC），然后在洗涤过程中释放出来。衣物干燥也可能有助于释放电动干燥机释放的化学物质。该结果对皮肤接触也有影响。

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  • 来源
    《Environmental Science & Technology》 |2016年第17期|9289-9297|共9页
  • 作者

    Amandeep Saini; Clara Thaysen; Liisa Jantunen; Rachel H. McQueen; Miriam L. Diamond;

  • 作者单位

    Department of Physical and Environmental Sciences, University of Toronto Scarborough, 1265 Military Trail, Toronto, Ontario MIC 1A4 Canada;

    Department of Earth Sciences, 22 Russell Street, University of Toronto, Toronto, Ontario M5S 3B1 Canada;

    Department of Earth Sciences, 22 Russell Street, University of Toronto, Toronto, Ontario M5S 3B1 Canada,Air Quality Processes Research Section, Environment and Climate Change Canada, 6248 Eighth Line, Egbert, Ontario LOL 1NO Canada;

    Department of Human Ecology, University of Alberta, Edmonton, Alberta T6G 2N1 Canada;

    Department of Physical and Environmental Sciences, University of Toronto Scarborough, 1265 Military Trail, Toronto, Ontario MIC 1A4 Canada,Department of Earth Sciences, 22 Russell Street, University of Toronto, Toronto, Ontario M5S 3B1 Canada;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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