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首页> 外文期刊>Environmental Science & Technology >Comparison of Hygroscopicity, Volatility, and Mixing State of Submicrometer Particles between Cruises over the Arctic Ocean and the Pacific Ocean
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Comparison of Hygroscopicity, Volatility, and Mixing State of Submicrometer Particles between Cruises over the Arctic Ocean and the Pacific Ocean

机译:北极和太平洋巡游之间亚微米级颗粒的吸湿性,挥发性和混合状态的比较

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摘要

Ship-borne measurements of ambient aerosols were conducted during an 11 937 km cruise over the Arctic Ocean (cruise 1) and the Pacific Ocean (cruise 2). A frequent nucleation event was observed during cruise 1 under marine influence, and the abundant organic matter resulting from the strong biological activity in the ocean could contribute to the formation of new particles and their growth to a detectable size. Concentrations of particle mass and black carbon increased with increasing continental influence from polluted areas. During cruise 1, multiple peaks of hygroscopic growth factor (HGF) of 1.1-1.2, 1.4, and 1.6 were found, and higher amounts of volatile organic species existed in the particles compared to that during cruise 2, which is consistent with the greater availability of volatile organic species caused by the strong oceanic biological activity (cruise 1). Internal mixtures of volatile and nonhygroscopic organic species, nonvolatile and less-hygroscopic organic species, and nonvolatile and hygroscopic nss-sulfate with varying fractions can be assumed to constitute the submicrometer particles. On the basis of elemental composition and morphology, the submicrometer particles were classified into C-rich mixture, S-rich mixture, C/S-rich mixture, Na-rich mixture, C/P-rich mixture, and mineral-rich mixture. Consistently, the fraction of biological particles (i.e., P-containing particles) increased when the ship traveled along a strongly biologically active area.
机译:在北冰洋(巡洋舰1)和太平洋(巡洋舰2)上进行了11937公里的航行期间,进行了船上环境气溶胶的测量。在航行1期间,在海洋的影响下观察到频繁的成核事件,并且海洋中强大的生物活性所产生的丰富有机物可能有助于形成新的粒子,并使它们的生长达到可检测的大小。颗粒质量和黑碳的浓度随着污染地区对大陆的影响而增加。在巡航1中,发现吸湿性生长因子(HGF)的多个峰分别为1.1-1.2、1.4和1.6,并且与巡航2中相比,颗粒中存在更多的挥发性有机物质。强烈的海洋生物活动引起的挥发性有机物种类(巡游1)。挥发性和非吸湿性有机物质,非挥发性和吸湿性较小的有机物质以及不挥发和吸湿性nss-硫酸盐的内部混合物(具有不同的分数)可以被认为构成了亚微米级颗粒。根据元素组成和形态,将亚微米级颗粒分为富C混合物,富S混合物,富C / S混合物,富Na混合物,富C / P混合物和富矿物质混合物。一致地,当船沿着强烈的生物活性区域行进时,生物颗粒(即,含P的颗粒)的比例增加。

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  • 来源
    《Environmental Science & Technology》 |2015年第20期|12024-12035|共12页
  • 作者单位

    National Leading Research Laboratory, School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea;

    National Leading Research Laboratory, School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea;

    National Leading Research Laboratory, School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea;

    National Leading Research Laboratory, School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea;

    Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-Gu, Incheon 406-840, Republic of Korea;

    Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-Gu, Incheon 406-840, Republic of Korea;

    Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-Gu, Incheon 406-840, Republic of Korea;

    National Leading Research Laboratory, School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, Republic of Korea;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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  • 正文语种 eng
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