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Polyfluorinated Compounds in Residential and Nonresidential Indoor Air

机译:住宅和非住宅室内空气中的多氟化合物

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摘要

Indoor air concentrations of fifteen volatile per- and polyfluorinated compounds (PFCs) (five fluorotelomer alcohols (FTOHs), three fluorotelomer acrylates (FTAs), three perfluorinated sulfonamido ethanols (FASEs), and three perfluorinated suHonamides (FASAs)) were determined in residential and nonresidential indoor air environments. Air samples were taken with passive samplers, consisting of XAD-4 impregnated polyurethane foam (PUF) disks in steel housings. Impregnated PUF disks were extracted by fluidized bed extraction (FBE) using methyl-rert-butyl ether/acetone (1:1) and analyzed by gas chromatography-mass spectrometry. Total PFC indoor air concentrations ranged from 8.2 to 458 ng m~(-3). Individual PFC concentrations were between 42 pg m~(-3) (6:2 FA) and 209 ng m~(-3) (8:2 FTOH). Concentrations of total FTOHs, FTAs, and FASAs + FASEs ranged from 0.2 to 152 ng m~(-3) (FTAs), from 3.3 to 307 ng m~(-3) (FTOHs), and from 4.4 to 148 ng m~(-3) (FASAs + FASEs). Most elevated individual, group, and total PFC concentrations were detected in two stores selling outdoor equipment, one furniture shop, and one carpet shop. Indoor air concentrations were several orders of magnitude higher than published outdoor air concentrations indicating indoor air environments as sources for PFCs to the atmosphere. Concentrations were used to estimate human exposure to investigated PFCs.
机译:在住宅和住宅中确定了15种挥发性全氟和多氟化合物(PFC)(五种氟调聚物醇(FTOH),三种氟调聚物丙烯酸酯(FTA),三种全氟磺酰胺基乙醇(FASEs)和三种全氟磺酰胺(FASAs)的室内空气浓度。非住宅室内空气环境。用被动采样器采集空气样本,该被动采样器由钢制外壳中的XAD-4浸渍聚氨酯泡沫(PUF)盘组成。使用甲基叔丁基醚/丙酮(1:1)通过流化床萃取(FBE)萃取浸渍的PUF圆盘,并通过气相色谱-质谱法进行分析。 PFC室内空气总浓度范围为8.2至458 ng m〜(-3)。各个PFC浓度在42 pg m〜(-3)(6:2 FA)和209 ng m〜(-3)(8:2 FTOH)之间。 FTOH,FTA和FASAs + FASE的总浓度范围为0.2至152 ng m〜(-3)(FTAs),3.3至307 ng m〜(-3)(FTOH)和4.4至148 ng m〜 (-3)(FASA + FASE)。在两家销售户外设备的商店,一家家具店和一家地毯店中,检测到大多数升高的个人,团体和总PFC浓度。室内空气浓度比公开的室外空气浓度高几个数量级,表明室内空气环境是大气中PFC的来源。使用浓度来估计人类接触所研究的PFC。

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  • 来源
    《Environmental Science & Technology》 |2010年第21期|p.8075-8081|共7页
  • 作者单位

    GKSS Research Center, Max Planck Str. 1,21502 Geesthacht, Germany,Leuphana University Luneburg, Scharnhorststr 1, 21335 Luneburg, Germany;

    rnGKSS Research Center, Max Planck Str. 1,21502 Geesthacht, Germany;

    rnGKSS Research Center, Max Planck Str. 1,21502 Geesthacht, Germany;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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  • 正文语种 eng
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