Comment on '1,1,2,2-Tetrachloroethane Reactions with OH~-, Cr(II), Granular Iron, and a Copper-Iron Bimetal: Insights from Product Formation and Associated Carbon Isotope Fractionation'

C. Noubactep

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Comment on '1,1,2,2-Tetrachloroethane Reactions with OH~-, Cr(II), Granular Iron, and a Copper-Iron Bimetal: Insights from Product Formation and Associated Carbon Isotope Fractionation'

机译：评论“与OH〜-，Cr（II），粒状铁和铜铁双金属的1,1,2,2-四氯乙烷反应：从产物形成和相关的碳同位素分馏中获得的见解”

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The paper by Eisner et al. (1) is ajustified attempt to contribute to the elucidation of the mechanism of reductive dehalo-genation of organohalides in real-world permeable reactive barriers (field Fe~0-H_2O systems or field Fe~0 PRBs ) by means of a very well-established scientific tool (carbon isotope fractionation). For this purpose, the authors used well-mixed batch experiments that are unfortunately known not to be representative for real-world conditions.

机译：Eisner等人的论文。（1）是一种合理的尝试，它通过非常好的方法来阐明现实世界的可渗透反应性势垒（场Fe〜0-H_2O系统或场Fe〜0 PRBs）中有机卤化物的还原性脱卤化机理。已建立的科学工具（碳同位素分馏）。为此，作者使用了充分混合的批处理实验，不幸的是，这些实验不能代表现实条件。

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来源
《Environmental Science & Technology》 |2007年第22期|p.7947-7948|共2页
作者
C. Noubactep;
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作者单位

Centre of Geosciences University of Goettingen Goldschmidtstrasse 3 D - 37077 Goettingen, Germany;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类环境化学;
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1. Response to Comment on '1,1,2,2-Tetrachloroethane Reactions with OH~-, Cr(II), Granular Iron, and a Copper-Iron Bimetal: Insights from Product Formation and Associated Carbon Isotope Fractionation' [J] . Martin Elsner, David M. Cwiertny, A. Lynn Roberts, Environmental Science & Technology . 2007,第22期

机译：对“ 1,1,2,2-四氯乙烷与OH〜-，Cr（II），粒状铁和铜铁双金属的反应：从产物形成和相关的碳同位素分馏的见解”评论的回应
2. 1,1,2,2-Tetrachloroethane Reactions with OH~-, Cr(II), Granular Iron, and a Copper—Iron Bimetal: Insights from Product Formation and Associated Carbon Isotope Fractionation [J] . MARTIN ELSNER, DAVID M. CWIERTNY, A. LYNN ROBERTS, Environmental Science & Technology . 2007,第11期

机译：OH〜-，Cr（II），粒状铁和铜铁双金属的1,1,2,2-四氯乙烷反应：从产物形成和相关的碳同位素分馏中获得的见解
3. Isotope fractionation of iron(III) in chemical exchange reactions using solvent extraction with crown ether [J] . Fujii T, Moynier F, Telouk P, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第38期

机译：使用冠醚萃取的化学交换反应中铁（III）的同位素分馏
4. Current Perspectives on the Mechanisms of Chlorohydrocarbon Degradation in Subsurface Environments: Insight from Kinetics, Product Formation, Probe Molecules, and Isotope Fractionation [C] . Martin Eisner, Thomas B. Hofstetter Symposium on aquatic redox chemistry . 2011

机译：目前对地下环境中氯烃基降解机制的目的：来自动力学，产品形成，探针分子和同位素分馏的洞察力
5. I. Predicting equilibrium stable isotope fractionations of iron, chlorine, and chromium. II. Oxygen-isotope investigation of Mesozoic and Cenozoic granitoids of the northeastern Great Basin, Nevada and Utah. [D] . Schauble, Edwin Arthur. 2002

机译：I.预测铁，氯和铬的平衡稳定同位素分馏。二。东北大盆地，内华达州和犹他州中生代和新生代花岗岩的氧同位素研究。
6. Evidence for equilibrium iron isotope fractionation by nitrate-reducing iron(II)-oxidizing bacteria [O] . A. Kappler, C.M. Johnson, H.A. Crosby, -1

机译：证据为平衡铁同位素分馏由硝酸盐还原铁（II）氧化细菌
7. 1,1,2,2-Tetrachloroethane Reactions with OH-, Cr(II), Granular Iron, and a Copper-Iron Bimetal: Insights from Product Formation and Associated Carbon Isotope Fractionation [O] . -1

机译：用OH-，Cr（II），颗粒铁和铜铁二丝醛的1,1,2,2-四氯乙烷反应：来自产物形成和相关碳同位素分馏的见解
8. Carbon Isotopic Fractionation during Formation of Macromolecular Organic Grain Coatings via FTT Reactions [R] . Nuth, J. A., Johnson, N. M., Elsila-Cook, J., 2011

机译：通过FTT反应形成大分子有机谷物涂层中的碳同位素分馏

Comment on '1,1,2,2-Tetrachloroethane Reactions with OH~-, Cr(II), Granular Iron, and a Copper-Iron Bimetal: Insights from Product Formation and Associated Carbon Isotope Fractionation'

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