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首页> 外文期刊>Environmental Science & Technology >Retrospective Monitoring of Alklphenols and Alkylphenol Monoethoxylates in Aquatic Biota from 1085 to 2001: Results from the German Environmental Specimen Bank
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Retrospective Monitoring of Alklphenols and Alkylphenol Monoethoxylates in Aquatic Biota from 1085 to 2001: Results from the German Environmental Specimen Bank

机译:追溯监测1085年至2001年水生生物群中的烷基酚和烷基酚一乙氧基化物:德国环境标本库的结果

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摘要

Breams (Abramis brama) and zebra mussels (Dreissena polymorpha) from freshwater, and common mussels (Mytilus edulis) from marine ecosystems, archived in the German Environmental Specimen Bank were analyzed forthe presence of 4-nonylphenol (NP), 4-tert-octylphenol (OP), nonylphenol monoethoxylate(NPlEO),andoctylphenolmonoethoxylate (OP1EO). The samples were collected in the German rivers Elbe, Rhine, and Saar, and in Lake Belau between 1992 and 2001, as well as in the North Sea and Baltic Sea between 1985 and 2001. The main purpose of the study was to investigate the effectiveness of imposed reduction measures regarding the use of alkylphenol ethoxylates. NP1EO and OP were detected in all breams. NP was predominantly above the limit of quantification (LOQ, 2 ng/g; all data on a wet weight basis), and OP1EO was mostly below the LOQ (0.2 ng/ g). Maximal concentrations of 112 ng/g NP, 259 ng/g NP1EO, 5.5 ng/g OP, and 2.6 ng/g OP1EO were found in Saar breams from 1994. NP was detected in all zebra mussels from the river Elbe (up to 41 ng/g), whereas in rather few samples OP and NP1EO were found at low levels. OP1EO was not detected in any sample. Concentrations in mussels and breams from the reference site Lake Belau were below the LOQ for all compounds. In marine biota NP was found until 1997 with maximum concentrations up to 9.7 ng/g, whereas NP1EO was detected at levels between 1.7 and 12.9 ng/g in very few samples collected at the end of the 1980s. A tendency of the concentrations to decrease was obvious for all sampling sites; it was most pronounced for NP1EO and NP after 1996/1997. The effectiveness of the reduction measures is most evident at the Saar sampling site Gudingen and the North Sea sampling site Eckwarder-horrne.
机译:分析了德国环境标本库中归档的淡水water(Abramis brama)和斑马贻贝(Dreissena polymorpha)以及海洋生态系统的普通贻贝(Mytilus edulis)中4-壬基酚(NP),4-叔辛基酚的存在。 (OP),壬基酚单乙氧基化物(NPlEO)和辛基酚单乙氧基化物(OP1EO)。样本是在1992年至2001年间在德国易北河,莱茵河和萨尔河以及贝劳湖以及1985年至2001年间在北海和波罗的海中采集的。本研究的主要目的是研究其有效性。关于使用烷基酚乙氧基化物的减少措施的说明。在所有中均检测到NP1EO和OP。 NP主要高于定量限(LOQ,2 ng / g;所有数据均以湿重计),OP1EO大多低于LOQ(0.2 ng / g)。自1994年以来,萨尔鱼中发现的最大NP浓度为112 ng / g NP,259 ng / g NP1EO,5.5 ng / g OP和2.6 ng / g OP1EO。在易北河中的所有斑马贻贝中均检测到NP(最高41 ng / g),而在极少的样品中发现OP和NP1EO含量低。在任何样品中均未检测到OP1EO。来自参考点贝劳湖的贻贝和鲷鱼的浓度均低于所有化合物的最低定量限。在海洋生物区系中,直到1997年才发现NP的最大浓度高达9.7 ng / g,而在1980年代末收集到的极少数样品中检测到的NP1EO含量在1.7至12.9 ng / g之间。在所有采样点,浓度降低的趋势都是明显的。在1996/1997年之后,NP1EO和NP最明显。减少措施的效果在萨尔采样点古丁根和北海采样点Eckwarder-horrne最为明显。

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