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首页> 外文期刊>Environmental Science & Technology >Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Contamination at Metal Recovery Facilities, Open Burn Sites, and a Railroad Car Incineration Facility
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Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Contamination at Metal Recovery Facilities, Open Burn Sites, and a Railroad Car Incineration Facility

机译:金属回收设施,露天焚烧场和火车焚化设施中的多氯二苯并二恶英和二苯并呋喃污染

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摘要

Soil and ash surface samples (n = 44) were collected from three historical metal recovery facilities where copper scrap was a dominant feed stream, three sites of open burning where evidence of copper recovery was visible, and from a railroad car incineration facility. Concentrations of polychlorinated dibenzo-p-dioxins (PCDD) and dibenzofurans (PCDF) are in the low parts per billion range with PCDF concentrations significantly lower in samples from the railroad car facility. In fly ash from a copper wire and aluminum scrap recovery facility, PCDD and PCDF concentrations are high, 50 and 460 ppm. Consistent with that cited for other combustion sources, ratios of PCDF to PCDD are mostly greater than 1. However, a lower ratio (0.4), is observed in samples from the railroad car incineration facility. OCDF and OCDD are significantly correlated with 2,3,7,8-TCDD toxicity equivalents (TEQ). These congeners may be inexpensively analyzed and may be useful as indicator chemicals at similar sites and facilities. Further investigations of metal recovery facilities and open burn sites worldwide are necessary.
机译:土壤和灰分表面样本(n = 44)是从三个历史悠久的金属回收设施(其中废铜为主要原料流),三个露天燃烧地点(可见铜回收的证据)以及有轨电车焚烧设施中收集的。多氯联苯对二恶英(PCDD)和二苯并呋喃(PCDF)的浓度在十亿分之几的低范围内,而来自铁路车辆设施的样品中PCDF的浓度则明显较低。在来自铜线和铝屑回收设施的粉煤灰中,PCDD和PCDF的浓度很高,分别为50和460 ppm。与其他燃烧源所引用的一致,PCDF与PCDD的比率大部分大于1。但是,在铁路车辆焚化设施的样品中观察到较低的比率(0.4)。 OCDF和OCDD与2,3,7,8-TCDD毒性当量(TEQ)显着相关。可以廉价地分析这些同类物,并可用作类似地点和设施的指示剂化学品。有必要对全球的金属回收设施和露天焚烧场进行进一步调查。

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