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首页> 外文期刊>Environmental toxicology and chemistry >POLYBROMINATED DIPHENYL ETHERS IN SURFACE SOILS FROM E-WASTE RECYCLING AREAS AND INDUSTRIAL AREAS IN SOUTH CHINA: CONCENTRATION LEVELS, CONGENER PROFILE, AND INVENTORY
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POLYBROMINATED DIPHENYL ETHERS IN SURFACE SOILS FROM E-WASTE RECYCLING AREAS AND INDUSTRIAL AREAS IN SOUTH CHINA: CONCENTRATION LEVELS, CONGENER PROFILE, AND INVENTORY

机译:中国南方电子废弃物回收区和工业区表层土壤中的多溴二苯醚:浓度水平,同类特征和库存

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摘要

Polybrominated diphenyl ethers (PBDEs) were determined in 60 surface soils from two e-waste recycling sites (Qingyuan and Guiyu, China) and their surrounding areas to assess the extent and influence of PBDEs from e-waste recycling sites on the surrounding areas. A total of 32 surface soils from industrial areas in South China were also investigated for comparison. The mean concentrations of total PBDEs in the e-waste recycling sites of Guiyu and Qingyuan were 2,909 and 3,230 ng/g dry weight, respectively, whereas the PBDE concentrations decreased dramatically (1-2 orders of magnitude) with increasing distance from the recycling site, suggesting that the e-waste recycling activities were the major source of PBDEs in the surrounding areas. Decabromodiphenyl ethers accounted for 77.0 to 85.8% of total PBDEs in e-waste recycling areas, whereas it accounted for 90.2% in industrial areas. Principal component analysis showed that the major source of PBDEs in e-waste recycling areas were a combination of penta-, octa-, and deca-BDE commercial formulations, whereas deca-BDE commercial formulations were the major source of PBDE congeners in industrial areas. The inventories of PBDEs gave preliminary estimates of 6.22 tons and 13.4 tons for the e-waste recycling areas and industrial areas. The results suggested that significantly higher PBDEs in the e-waste recycling sites have already affected surrounding areas negatively within a relatively large distance. Because of the environmental persistence, bioaccumulation, and toxicity of PBDEs, improving the recycling techniques employed at such facilities and developing e-waste management policies are necessary.
机译:在两个电子废物回收站(中国清远和贵屿)及其周边地区的60个表层土壤中测定了多溴联苯醚(PBDEs),以评估来自电子废物回收站的PBDEs的程度和影响。总共对来自华南工业区的32种表层土壤进行了调查,以进行比较。贵屿和清远电子垃圾回收站的多溴二苯醚总平均浓度分别为干重2909 ng / g和3230 ng / g,而随着距回收站距离的增加,多溴二苯醚的浓度急剧下降(1-2个数量级)。 ,表明电子废物回收活动是周边地区多溴二苯醚的主要来源。在电子废物回收领域,十溴二苯醚占多溴二苯醚总量的77.0%至85.8%,而在工业领域则占90.2%。主成分分析表明,电子废物回收地区的多溴二苯醚主要来源是五溴,八溴和十溴二苯醚商业配方的组合,而十溴二苯醚商业配方是工业领域中多溴二苯醚同源物的主要来源。 PBDEs的库存初步估计为电子垃圾回收区和工业区为6.22吨和13.4吨。结果表明,电子废物回收站中较高的多溴二苯醚已经在相对较大的距离内对周围地区产生了负面影响。由于多溴二苯醚的环境持久性,生物蓄积性和毒性,因此有必要改进此类设施中采用的再循环技术并制定电子废物管理政策。

著录项

  • 来源
    《Environmental toxicology and chemistry》 |2011年第12期|p.2688-2696|共9页
  • 作者单位

    State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Chinese Academy of Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Chinese Academy of Sciences, Guangzhou, China,Graduate School of the Chinese Academy of Sciences, Beijing, China,Guangdong Institute for Drug Control, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Chinese Academy of Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Chinese Academy of Sciences, Guangzhou, China,Graduate School of the Chinese Academy of Sciences, Beijing, China;

    Guangdong Institute of Eco-Environment and Soil Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Chinese Academy of Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Chinese Academy of Sciences, Guangzhou, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    polybrominated diphenyl ethers; E-waste; concentration level; congener profile; mass inventory;

    机译:多溴二苯醚;电子垃圾浓度水平;同类资料;大量库存;

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