首页> 外文期刊>Environmental toxicology and chemistry >PASSIVE SAMPLER-DERIVED AIR CONCENTRATIONS FOR POLYBROMINATED DIPHENYL ETHERS AND POLYCYCLIC AROMATIC HYDROCARBONS IN KUWAIT
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PASSIVE SAMPLER-DERIVED AIR CONCENTRATIONS FOR POLYBROMINATED DIPHENYL ETHERS AND POLYCYCLIC AROMATIC HYDROCARBONS IN KUWAIT

机译:科威特聚溴二苯醚和多环芳烃的被动采样空气浓度

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摘要

The present study presents, to our knowledge, the first ambient air data for a range of polybrominated diphenyl ethers (PBDEs) and polycyclic aromatic hydrocarbons (PAHs) in Kuwait. This was achieved by concurrently deploying polyurethane foam-disk passive samplers at 14 sites over a six-week period. Calculated mean Σ_5PBDE concentrations (sum of brominated diphenyl ethers [BDEs] 47, 99, 100, 153, and 154) ranged from 2.5 to 32 pg/m~3 of air, with BDE 47 contributing between 39 and 65% of the 睵BDEs detected. Differences in relative concentrations were observed between sites, with higher concentrations measured close to suspected sources. Calculated 2PAH concentrations ranged from 5 to 13 ng/m~3 (mean, 8.3 ng/m~3). The compound distribution was dominated by three- and four-ring compounds, which constituted approximately 90% of the ΣPAHs, with phen-anthrene contributing approximately 35%. However, the proportion of five- and six-ring PAHs increased around the "oil lakes," which were formed by the torching of oil wells during the 1991 Gulf War. The oil lakes are a reservoir of PAHs that will continue feeding the atmosphere as long as they remain untreated.
机译:据我们所知,本研究提供了科威特一系列范围内的多溴联苯醚(PBDEs)和多环芳烃(PAHs)的首个环境空气数据。这是通过在六个星期的时间内在14个地点同时部署聚氨酯泡沫盘式被动采样器来实现的。计算出的平均Σ_5PBDE浓度(溴化二苯醚[BDE] 47、99、100、153和154的总和)范围为2.5至32 pg / m〜3空气,其中BDE 47占the的39%至65%。检测到BDE。在站点之间观察到相对浓度差异,在可疑来源附近测得较高浓度。计算得出的2PAH浓度范围为5到13 ng / m〜3(平均8.3 ng / m〜3)。该化合物的分布主要由三环和四环化合物组成,约占ΣPAH的90%,而菲-蒽占约35%。但是,五环和六环PAH的比例在“油湖”周围增加了,“油湖”是1991年海湾战争期间油井被火烧形成的。油湖是多环芳烃的蓄水池,只要不加以处理,它们就会继续向大气中供气。

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