Multiresidue Methods for the Determination of Organic　Micropollutants and Their Metabolites in Fish Matrices

Molbert Noelie; Alliot Fabrice; Santos Raphael; Chevreuil Marc; Mouchel Jean-Marie; Goutte Aurelie

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Multiresidue Methods for the Determination of Organic　Micropollutants and Their Metabolites in Fish Matrices

机译：用于测定有机微量胶质剂和鱼类代谢物的多迹方法

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Two analytical methods were developed for the determination of 48 organic compounds and 20 of their main by-products in fish matrices. The targeted compounds belong to various chemical classes of metabolizable (phthalates, polycyclic aromatic hydrocarbons, insecticides [pyrethroids and N,N-diethyl-meta-toluamide]) and legacy (organochlorine pesticides, polychlorinated biphenyls, polybrominated diphenyl ethers) pollutants. Analyses were performed by gas and liquid chromatography-tandem mass spectrometry in multiple reaction monitoring (MRM) and dynamic MRM, respectively. Method performances were satisfactory, with results meeting the validation criteria because they achieved good linearity responses, recovery, precision, and accuracy for most of the 68 investigated compounds. The methods were then applied on 3 feral chub (Squalius cephalus) collected from the Marne hydrographic network (France). Twenty-six parent compounds and 5 metabolites were systematically detected in fish matrices, with substantial concentration variability within and among individuals. Phthalates and pyrethroids accounted for most of the pollutant load. Metabolite concentrations in liver samples exceeded those of parent molecules in fish muscle. The present study presents 2 reliable methods for the determination of a wide range of contaminants and underlines the importance of metabolite analysis for a more comprehensive understanding of pollutant bioaccumulation and fate in aquatic organisms. Environ Toxicol Chem 2019;00:1-13. (c) 2019 SETAC

机译：开发了两种分析方法，用于测定在鱼类基质中的48个有机化合物和20个主要副产物中。靶向化合物属于各种化学类代谢（邻苯二甲酸盐，多环芳烃，杀虫剂[拟除虫菊酯和N，N-二乙基 - 甲苯胺]）和遗留（有机氯农药，多氯联苯，多溴二苯醚）污染物。通过气体和液相色谱 - 串联质谱法分别在多重反应监测（MRM）和动态MRM中进行分析。方法性能令人满意，结果满足验证标准，因为它们实现了良好的线性反应，回收，精度和准确性，对大部分68种研究化合物。然后将该方法施用于来自Marne水文网络（法国）收集的3个野生Chub（Squalius Cephalus）。在鱼类矩阵中系统地检测到二十六种母体化合物和5个代谢物，具有在个体内部和中间的浓度变异性。邻苯二甲酸酯和拟除虫菊酯占大多数污染物负荷。肝脏样品中的代谢物浓度超过了鱼肌中的母体分子的浓度。本研究提出了2种可靠的方法，用于测定各种污染物，并强调代谢物分析的重要性，以更全面地了解水生生物中的污染物生物累积和命运。环境毒素科学2019; 00：1-13。（c）2019 Setac

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来源
《Environmental toxicology and chemistry》 |2019年第9期|1866-1878|共13页
作者
Molbert Noelie; Alliot Fabrice; Santos Raphael; Chevreuil Marc; Mouchel Jean-Marie; Goutte Aurelie;
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作者单位

Sorbonne Univ UMR METIS Milieux Environm Transferts & Interact CNRS Ecole Prat Hautes Etud Paris France;

Sorbonne Univ UMR METIS Milieux Environm Transferts & Interact CNRS Ecole Prat Hautes Etud Paris France|PSL Res Univ UMR METIS Milieux Environm Transferts & Interact EPHE Paris France;

Univ Appl Sci Western Switzerland HEPIA Haute Ecole Paysage Ingn & Architecture Gen Ecol & Engn Aquat Syst Res Grp Geneva Switzerland;

Sorbonne Univ UMR METIS Milieux Environm Transferts & Interact CNRS Ecole Prat Hautes Etud Paris France|PSL Res Univ UMR METIS Milieux Environm Transferts & Interact EPHE Paris France;

Sorbonne Univ UMR METIS Milieux Environm Transferts & Interact CNRS Ecole Prat Hautes Etud Paris France;

Sorbonne Univ UMR METIS Milieux Environm Transferts & Interact CNRS Ecole Prat Hautes Etud Paris France|PSL Res Univ UMR METIS Milieux Environm Transferts & Interact EPHE Paris France;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类
关键词
Persistent organic micropollutants; Phthalates; By-products; Polycyclic aromatic hydrocarbons; Pyrethroid; Flame retardants;

机译：持久性有机微渗透物;邻苯二甲酸盐;副产品;多环芳烃;拟除虫菊酯;阻燃剂;

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专利

1. Multiresidue Methods for the Determination of Organic　Micropollutants and Their Metabolites in Fish Matrices [J] . Molbert Noelie, Alliot Fabrice, Santos Raphael, Environmental toxicology and chemistry . 2019,第9期

机译：多残留法测定鱼基质中有机微污染物及其代谢物
2. Multiresidue method for the determination of 13 pesticides in three environmental matrices: Water, sediments and fish muscle [J] . Lazartigues A., Fratta C., Baudot R., Talanta: The International Journal of Pure and Applied Analytical Chemistry . 2011,第3期

机译：多残留法测定水，沉积物和鱼肉三种环境基质中的13种农药
3. Multiresidue analytical method for the determination of 41 multiclass organic pollutants in mussel and fish tissues and biofluids by liquid chromatography coupled to tandem mass spectrometry [J] . Mijangos Leire, Ziarrusta Haizea, Zabaleta Itsaso, Analytical and bioanalytical chemistry . 2019,第2期

机译：液相色谱法测定贻贝和鱼类组织和生物流体中41个多烷类有机污染物的多迹分析方法，液相色谱耦合到串联质谱法
4. Multiresidue Determination of Saraftoxacin, Difloxacin, Norfloxacin, and Pefloxacin in Fish using an Enzyme-Linked Immunosorbent Assay [C] . Jiang Jinqing, Zhang Haitang, Wang Ziliang International Conference on Environment Science and Biotechnology . 2013

机译：使用酶联免疫吸附测定法测定鱼类糖酸胞外毒素，二氧化酮，诺氟沙星和Pefloxacin
5. Part A: Speciation of aluminum metabolites in biological matrices employing chemical neutron activation analysis. Part B: Evaluation of methods for the determination of trimethylselenonium ion in urine [D] . Shoop, David Mark 1996

机译：A部分：采用化学中子活化分析的生物基质中铝代谢物的形态。 B部分：尿液中三甲基硒离子测定方法的评价
6. Multi LC-MS/MS and LC-HRMS Methods for Determination of 24 Mycotoxins including Major Phase I and II Biomarker Metabolites in Biological Matrices from Pigs and Broiler Chickens [O] . Marianne Lauwers, Siegrid De Baere, Ben Letor, 2018

机译：多种LC-MS / MS和LC-HRMS方法测定猪和肉鸡生物基质中24种霉菌毒素，包括I和II期主要生物标志物代谢物
7. Simultaneous ozonation of 90 organic micropollutants including illicit drugs and their metabolites in different water matrices [O] . Garyfalia A. Zoumpouli, Fernanda Siqueira Souza, Bruce Petrie, 2020

机译：同时臭氧化90种有机微量舒适剂，包括非法药物及其在不同水矩阵中的代谢物
8. Analytical Methods For THE DETERMINATION OF CAESIUM -I37, STRONTIUM-89 AND-90 IN MILK, VEGETATION, ORGANIC ION EXCHANGE RESINS, SEAWEED AND FISH FLESH, AND STRONTIUM -89 AND -90 IN BONE [R] . 1960

机译：用于测定牛奶，植物，有机离子交换树脂，海藻和鱼类中的铯-I37，锶-89和-90的分析方法以及骨中-89和-90的分析方法

Multiresidue Methods for the Determination of Organic Micropollutants and Their Metabolites in Fish Matrices

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Multiresidue Methods for the Determination of Organic　Micropollutants and Their Metabolites in Fish Matrices