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Functional Nanocomposite Poly(phenylene sulphide) Fibres - Preliminary Studies

机译:功能性纳米复合聚苯硫醚纤维-初步研究

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摘要

Composite poly(phenylene sulphide) (PPS) fibres and nonwovens were obtained by the melt blowing method. A specially designed twin screw extruder was used which allowed to perform several mixing cycles prior to final extrusion. Multiwall carbon nanotubes (CNTs) and carbonyl iron microparticles were used as the additives. To obtain possibly good dispersion of the modifiers in the polymer melt, the CNTs were first dispersed in N-methyl-2-pyrrolidone and Fe microparticles were dispersed in polyethylene wax. Rheological characteristics of the melts and bulk composites, such as viscosity, loss and storage moduli, are similar to those reported by other groups; however, the contents of additives must be lower than in the case of bulk materials to assure satisfactory melt spinability. The fibres obtained show satisfactory mechanical characteristics and electromagnetic screening efficiency in the GHz region.
机译:通过熔喷法获得复合聚苯硫醚(PPS)纤维和非织造布。使用专门设计的双螺杆挤出机,在最终挤出之前可以进行几个混合循环。使用多壁碳纳米管(CNT)和羰基铁微粒作为添加剂。为了获得改性剂在聚合物熔体中可能的良好分散,首先将CNT分散在N-甲基-2-吡咯烷酮中,然后将Fe微粒分散在聚乙烯蜡中。熔体和散装复合材料的流变特性,例如粘度,损耗和储能模量,与其他研究组报道的相似。但是,为了确保令人满意的熔体纺丝性,添加剂的含量必须低于散装材料的含量。所获得的纤维在GHz区域显示出令人满意的机械特性和电磁屏蔽效率。

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