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Activated carbons and amine-modified materials for carbon dioxide capture: a review

机译:用于捕获二氧化碳的活性炭和胺改性材料:综述

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摘要

Rapidly increasing concentration of CO_2 in the atmosphere has drawn more and more attention in recent years, and adsorption has been considered as an effective technology for CO_2 capture from the anthropogenic sources. In this paper, the attractive adsorbents including activated carbons and amine-modified materials were mainly reviewed and discussed with particular attention on progress in the adsorbent preparation and CO_2 adsorption capacity. Carbon materials can be prepared from different precursors including fossil fuels, biomass and resins using the carbonization-activation or only activation process, and activated carbons prepared by KOH activation with high CO_2 adsorbed amount were reviewed in the preparation, adsorption capacity as well as the relationship between the pore characteristics and CO_2 adsorption. For the amine-modified materials, the physical impregnation and chemical graft of polyethylenimine (PEI) on the different porous materials were introduced in terms of preparation method and adsorption performance as well as their advantages and disadvantages for CO_2 adsorption. In the last section, the issues and prospect of solid adsorbents for CO_2 adsorption were summarized, and it is expected that this review will be helpful for the fundamental studies and industrial applications of activated carbons and amine-modified adsorbents for CO_2 capture.
机译:近年来,大气中CO_2浓度的迅速提高引起了越来越多的关注,吸附被认为是从人为来源捕获CO_2的有效技术。本文主要对包括活性炭和胺改性材料在内的有吸引力的吸附剂进行了综述和讨论,特别是对吸附剂制备和CO_2吸附能力的研究。可以通过碳化活化或仅活化过程,从化石燃料,生物质和树脂等不同的前体中制备碳材料,并综述了通过KOH活化制备的具有高CO_2吸附量的活性炭,吸附量及其关系。孔特性与CO_2吸附之间的关系对于胺改性材料,从制备方法和吸附性能以及它们对CO_2吸附的优缺点出发,介绍了聚乙烯亚胺(PEI)在不同多孔材料上的物理浸渍和化学接枝。在最后一部分中,总结了用于CO_2吸附的固体吸附剂的问题和前景,并希望此综述对用于捕获CO_2的活性炭和胺改性吸附剂的基础研究和工业应用有所帮助。

著录项

  • 来源
    《Frontiers of environmental science & eng》 |2013年第3期|326-340|共15页
  • 作者单位

    State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University, Beijing 100084, China;

    State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University, Beijing 100084, China ,Tsinghua University - Veolia Environment Joint Research Center for Advanced Technology, Tsinghua University, Beijing 100084, China;

    State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University, Beijing 100084, China;

    State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University, Beijing 100084, China;

    State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University, Beijing 100084, China;

    State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University, Beijing 100084, China ,Tsinghua University - Veolia Environment Joint Research Center for Advanced Technology, Tsinghua University, Beijing 100084, China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    adsorption capacity; CO_2 capture; activated carbon; amine-impregnated adsorbents;

    机译:吸附能力二氧化碳捕获;活性炭;胺浸渍的吸附剂;

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