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首页> 外文期刊>Fuel >Thermal/catalytic cracking of liquid hydrocarbons for the production of olefins: A state-of-the-art review II: Catalytic cracking review
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Thermal/catalytic cracking of liquid hydrocarbons for the production of olefins: A state-of-the-art review II: Catalytic cracking review

机译:液态烃的热/催化裂化用于生产烯烃:最新技术综述II:催化裂化综述

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摘要

Light olefins such as ethylene and propylene, are considered as main raw materials for the production of numerous plastic materials, synthesis fibers and rubbers in the petrochemical industry. The conventional process for the production of light olefins is thermal cracking in the presence of steam called Steam Cracking (SC). This has been the main technology for the production of olefins for more than ninety years. This technology has reached to its full capacity and cannot accommodate excessive demands of the petrochemical industry although still 95% of the light olefins are produced by this technology. In addition there are a few drawbacks for this technology such as en extensive energy consumption, and production of greenhouse gasses. An alternative and promising route for the production of light olefins which consumes less energy and produces fewer pollutants to the environment is Thermal Catalytic Cracking (TCC). This paper reviews the main research works done on the process in the literature in the last five decades. An eight-lump mathematical model is presented for the catalytic cracking kinetics. Some of the main experimental laboratory setup systems in the world have also been reviewed and parts of the results are presented and discussed. (C) 2016 Elsevier Ltd. All rights reserved.
机译:轻质烯烃,例如乙烯和丙烯,被认为是石油化工行业生产多种塑料,合成纤维和橡胶的主要原料。生产轻质烯烃的常规方法是在称为蒸汽裂化(SC)的蒸汽存在下进行热裂化。九十多年来,这一直是生产烯烃的主要技术。尽管仍有95%的轻质烯烃是通过该技术生产的,但该技术已达到其最大产能,无法满足石化行业的过度需求。另外,该技术还存在一些缺点,例如大量的能源消耗以及温室气体的产生。热催化裂化(TCC)是生产耗能少,对环境产生较少污染物的轻质烯烃的另一种有希望的途径。本文回顾了过去五十年来有关该过程的主要研究成果。针对催化裂化动力学,提出了一个八集数学模型。还审查了世界上一些主要的实验实验室设置系统,并介绍和讨论了部分结果。 (C)2016 Elsevier Ltd.保留所有权利。

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