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首页> 外文期刊>Fuel >Vapor pressure measurements of ethanol-isooctane and 1-butanol-isooctane systems using a new ebulliometer
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Vapor pressure measurements of ethanol-isooctane and 1-butanol-isooctane systems using a new ebulliometer

机译:使用新型雾度计测量乙醇-异辛烷和1-丁醇-异辛烷系统的蒸气压

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摘要

A new, simpler ebulliometer has been developed to accurately measure the vapor pressure of ethanol-isooctane and 1-butanol-isooctane systems at various mixture compositions. The reliability of the experimental apparatus was validated by comparing the experimental data with published data for pure isooctane and ethanol and ethanol-isooctane system. Our data were in good agreement with the published data, with a deviation of less than 1.9%. The vapor pressure of an ethanol-isooctane mixture was initially elevated by the addition of ethanol until the ethanol concentration reached 0.3 mass fractions, then dropped at concentrations above 0.7 mass fractions. For a 1 -butanol-isooctane system, the vapor pressure decreased with increasing 1-butanol concentrations. The experimental data were correlated using the Wilson, Non-Random Two-Liquid (NRTL), and Universal Quasi-Chemical (UNIQUAC) activity coefficient models with an average absolute deviation in the vapor pressures of 3.5%, 3.3%, and 6.1%, respectively.
机译:已开发出一种新的,更简单的浊度仪,以精确测量各种混合物成分下的乙醇-异辛烷和1-丁醇-异辛烷体系的蒸气压。通过将实验数据与已发布的纯异辛烷和乙醇以及乙醇-异辛烷体系的数据进行比较,验证了该实验设备的可靠性。我们的数据与已发布的数据非常吻合,偏差小于1.9%。首先通过添加乙醇来提高乙醇-异辛烷混合物的蒸气压,直到乙醇浓度达到0.3质量分数,然后以高于0.7质量分数的浓度下降。对于1-丁醇-异辛烷体系,蒸气压随着1-丁醇浓度的增加而降低。使用威尔逊(Wilson),非随机两液(NRTL)和通用拟化学(UNIQUAC)活性系数模型对实验数据进行了关联,其蒸气压的平均绝对偏差分别为3.5%,3.3%和6.1%,分别。

著录项

  • 来源
    《Fuel》 |2013年第5期|47-51|共5页
  • 作者单位

    Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Campus ITS Sukolilo, Surabaya 6011J, Indonesia;

    Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Campus ITS Sukolilo, Surabaya 6011J, Indonesia;

    Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Campus ITS Sukolilo, Surabaya 6011J, Indonesia;

    Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology (ITS), Campus ITS Sukolilo, Surabaya 6011J, Indonesia;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    ebulliometer; ethanol; isooctane; vapor pressure;

    机译:湿度计乙醇异辛烷蒸汽压力;

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