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Influence of different catalyst deactivation models in a validated simulator of an industrial UOP FCC unit with high-efficiency regenerator

机译:经验证的具有高效再生器的工业UOP FCC装置的仿真器中不同催化剂失活模型的影响

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摘要

Two types of deactivation functions are usually employed when modelling catalytic cracking: the time-based models and the coke-on-catalyst models. In this paper, a comparison is made between these two types of deactivation functions in the simulation of an industrial UOP fluid catalytic cracking (FCC) unit with high-efficiency regenerator. For this purpose, a FCC mathematical dynamic model, previously presented and validated, is used. The dynamic responses to perturbations of+10% increase in the combustor air mass flowrate and +5% in the feedstock flow, were studied. The results for these perturbations show that the slight differences observed were due to the fact that the coke-on-catalyst approach takes into account the coke content present at the riser inlet.
机译:在对催化裂化进行建模时,通常会使用两种类型的失活函数:基于时间的模型和催化剂上的焦炭模型。在本文中,在模拟具有高效再生器的工业UOP流化催化裂化(FCC)单元时,将这两种类型的停用功能进行了比较。为此,使用了先前介绍和验证的FCC数学动态模型。研究了燃烧器空气质量流量增加10%和原料流量增加5%对扰动的动态响应。这些扰动的结果表明,观察到的细微差异是由于以下事实:催化剂上的焦炭方法考虑了立管进口处存在的焦炭含量。

著录项

  • 来源
    《Fuel》 |2012年第2012期|p.97-108|共12页
  • 作者单位

    IFP Energies Nouvelles - Lyon, Process Design and Modeling Division, Rond-point de I'echangeur de Solaize, BP 3, 69360 Solaize, France;

    IBB - Institute for Biotechnology and Bioengineering, Catalysis and Reaction Engineering Research Croup, Instituto Superior Tecnico/Universidade Tecnica de Lisboa,Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal;

    IBB - Institute for Biotechnology and Bioengineering, Catalysis and Reaction Engineering Research Croup, Instituto Superior Tecnico/Universidade Tecnica de Lisboa,Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal;

    CEPSI-PSE Croup, Department of Chemical Engineering, University of Coimbra, Rua Silvio Lima, 3030-790 Coimbra, Portugal;

    IFP Energies Nouvelles - Lyon, Process Design and Modeling Division, Rond-point de I'echangeur de Solaize, BP 3, 69360 Solaize, France,In memory of Prof. Fernando Ramoa Ribeiro, who has recently deceased;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    fluid catalytic cracking; catalyst deactivation; mathematical modelling; simulation;

    机译:流化催化裂化催化剂失活;数学建模;模拟;

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