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Organic geochemical comparison of asphaltites of Slrnak area with the oils of the Raman and Dinçer fields in Southeastern Turkey

机译:土耳其东南部Slrnak地区沥青质与Raman和Dinçer油田油的有机地球化学比较

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摘要

Fifty-five samples of asphaltites from 12 different veins in (S)lrnak area and two oil samples from Raman and Dinner Oil fields in South East (SE) Turkey have been analyzed by organic geochemical methods (total organic carbon, rock-eval pyrolysis, gas chromatography of saturated fractions, gas chromatography-mass spectrometry and stable carbon isotope). The total organic carbon (TOC) contents in asphaltites ran ged from 12% to 65%. The T_(max)values range between 428 ℃ and 465 ℃. The hydrogen index (HI) values vary between 270 and 531 mg HC/g TOC. The levels of biodegradation of the asphaltites were studied by GC analyses of the saturated fractions and none to moderate biodegradation has been found. Maturity of the asphaltite samples were assessed biomarker ratios provided by GC-MS analysis. Stable carbon isotope ((~13)C) analyses of Raman-Dinner oils produced values about -21‰ and the asphaltene fractions of the asphaltite samples revealed similar values about 26.8‰. It is presumed that the asphaltites are of oil ori gin and has been solidified in veins close to surface and the geochemical correlation and encountering to the oil seeps in crevices suggest similarities between the (S)lrnak area asphaltites and Raman-Dinner oils.
机译:通过有机地球化学方法(总有机碳,岩溶热解,饱和馏分的气相色谱,气相色谱-质谱和稳定的碳同位素)。沥青岩中的总有机碳(TOC)含量在12%至65%之间。 T_(max)值的范围为428℃至465℃。氢指数(HI)值在270至531 mg HC / g TOC之间变化。通过饱和组分的GC分析研究了沥青质的生物降解水平,没有发现到中度生物降解。通过GC-MS分析评估了沥青质样品的成熟度。拉曼-丁纳油的稳定碳同位素((〜13)C)分析得出的值约为-21‰,而沥青质样品的沥青质馏分显示出的相似值约为26.8‰。据推测,该沥青质是石油来源的,并且已经在靠近地表的静脉中凝固,并且地球化学的相关性以及在裂缝中遇到油渗漏表明(S)lrnak地区的沥青质与拉曼-丁纳油之间存在相似性。

著录项

  • 来源
    《Fuel》 |2011年第4期|p.1575-1583|共9页
  • 作者

    Orhan Kavak;

  • 作者单位

    Department of Mining Engineering, Faculty of Engineering, Dxcle University, TR-21280 Diyarbakir, Turkey;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    asphaltite; raman-dinner oil; southeastern turkey; (s)lrnak area;

    机译:沥青质拉曼晚餐油;东南土耳其(s)lrnak地区;

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