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Preparation of KF/CaO nanocatalyst and its application in biodiesel production from Chinese tallow seed oil

机译:KF / CaO纳米催化剂的制备及其在牛脂种子油生产生物柴油中的应用

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摘要

KF/CaO nanocatalyst was prepared by using impregnation method and used to convert Chinese tallow seed oil to biodiesel. The effects of different preparation conditions on biodiesel yield were investigated and the structure of the catalyst was characterized. Transmission electron microscopy (TEM) photograph showed that the catalyst had porous structure with the particle size of 30-100 nm. Brunauer-Emmet-Teller (BET) analysis indicated that the catalyst specific surface area was 109 m~2 g~(-1) and average pore size was 97 nm. X-ray diffractometer (XRD) analysis demonstrated that the new crystal KCaF_3 was formed in catalyst, which enhanced catalytic ability. Under the optimal conditions, the biodiesel yield was 96.8% in the presence of as-prepared KF/CaO catalyst, showing potential applications of catalyst in biodiesel industry.
机译:采用浸渍法制备了KF / CaO纳米催化剂,用于将牛脂种子油转化为生物柴油。研究了不同制备条件对生物柴油收率的影响,并表征了催化剂的结构。透射电子显微镜(TEM)照片显示该催化剂具有30-100nm粒径的多孔结构。 Brunauer-Emmet-Teller(BET)分析表明,催化剂的比表面积为109 m〜2 g〜(-1),平均孔径为97 nm。 X射线衍射仪(XRD)分析表明,新型晶体KCaF_3在催化剂中形成,提高了催化能力。在最佳条件下,在制备的KF / CaO催化剂存在下,生物柴油产率为96.8%,表明该催化剂在生物柴油工业中的潜在应用。

著录项

  • 来源
    《Fuel》 |2010年第9期|P.2267-2271|共5页
  • 作者单位

    College of Science, Huazhong Agricultural University, Wuhan 430070, China;

    College of Science, Huazhong Agricultural University, Wuhan 430070, China;

    College of Science, Huazhong Agricultural University, Wuhan 430070, China;

    College of Science, Huazhong Agricultural University, Wuhan 430070, China;

    College of Science, Huazhong Agricultural University, Wuhan 430070, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    biodiesel; nanocatalyst; chinese tallow seed oil; transesterification;

    机译:生物柴油纳米催化剂牛油籽油;酯交换;

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