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The effect of methods of preparation on the performance of cupric chloride-impregnated sorbents for the removal of mercury from flue gases

机译:制备方法对氯化铜浸渍吸附剂去除烟气中汞的性能的影响

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摘要

Cupric chloride-impregnated carbon sorbents (CuCl_2-ACs) showed comparable performance in elemental mercury (Hg~0) oxidation and adsorption to a brominated activated carbon sorbent (Darco Hg-LH) in our previously reported experimental studies using fixed-bed and entrained-flow systems. This study tested several CuCl_2-ACs prepared in different solvents to investigate the effects of solvents on the Hg~0 removal capability of CuCl_2-ACs and find the most efficient and economical method of sorbent preparation. The performance of CuCl_2-ACs prepared in different solvents was also examined with respect to surface tension and pH of solvents. As a result, the sorbents prepared in isopropyl alcohol and acetone showed the best performance in these tests, but low surface tension and pH of isopropyl alcohol and acetone were not found to be critical factors.
机译:氯化铜浸渍的碳吸附剂(CuCl_2-ACs)在元素汞(Hg〜0)氧化和吸附方面的性能与溴化活性炭吸附剂(Darco Hg-LH)相当,在我们先前报道的使用固定床和夹带式吸附剂的实验研究流系统。本研究测试了几种在不同溶剂中制备的CuCl_2-ACs,以研究溶剂对CuCl_2-ACs的Hg〜0去除能力的影响,并找到最有效,最经济的吸附剂制备方法。相对于表面张力和溶剂的pH,还检查了在不同溶剂中制备的CuCl_2-AC的性能。结果,在异丙醇和丙酮中制备的吸附剂在这些测试中显示出最佳性能,但是发现异丙醇和丙酮的低表面张力和pH值不是关键因素。

著录项

  • 来源
    《Fuel》 |2009年第10期|2053-2056|共4页
  • 作者单位

    Department of Civil and Environmental Engineering, University of Cincinnati, Cincinnati, OH 45221, United States;

    Department of Civil and Environmental Engineering, University of Cincinnati, Cincinnati, OH 45221, United States;

    Department of Civil and Environmental Engineering, University of Cincinnati, Cincinnati, OH 45221, United States;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    mercury emissions control; surface tension; cupric chloride;

    机译:汞排放控制;表面张力;氯化铜;

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