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A critical approach to viscosity index

机译:粘度指数的关键方法

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摘要

The viscosity index (VI) is a useful tool for lubricant users and refiners, since it is a measure of the effect of temperature changes on the viscosity of the oil. However, it was found that the viscosity index does not correlate with the flow activation energy E_a, which is the theoretically defined dependence of the viscosity on temperature. In this way, two oils may have the same flow activation energy but a viscosity index varying by up to 120. We therefore believe that the VI does not always give a proper representation of the effect of temperature on the kinematic viscosity.rn~(13)C NMR spectroscopy was used to identify the molecules with a high VI Twenty different oil samples produced from eight different vacuum gas oils with viscosity indices ranging from - 104 to 146 were analyzed and key parameters identified for high VI molecules: long alkyl chains, methyl branching in the centre of the molecule, low content of aromatic compounds, no ethyl branching and no tertiary carbons.rnA correlation based on four selected peaks was developed, giving a very good prediction of the viscosity index.
机译:粘度指数(VI)是润滑剂用户和精炼商的有用工具,因为它可以衡量温度变化对机油粘度的影响。然而,发现粘度指数与流动活化能E_a不相关,流动活化能E_a是理论上定义的粘度对温度的依赖性。这样,两种油可能具有相同的流动活化能,但粘度指数最多变化120。因此,我们认为VI不能始终正确地表示温度对运动粘度的影响。rn〜(13 C NMR光谱法用于鉴定具有高VI的分子。分析了八种不同的真空瓦斯油生产的二十种不同的油样,粘度指数范围为-104至146,并鉴定了高VI分子的关键参数:长烷基链,甲基在分子中心支化,芳族化合物含量低,没有乙基支化且没有叔碳。建立了基于四个选定峰的rn相关性,从而很好地预测了粘度指数。

著录项

  • 来源
    《Fuel》 |2009年第11期|2199-2206|共8页
  • 作者单位

    Haldor Topsoe A/S, Nymollevej 55, 2800 Lyngby, Denmark;

    University of Aveiro, Department of Chemistry, CICECO and QOPNA, 3810-193 Aveiro, Portugal;

    University of Aveiro, Department of Chemistry, CICECO and QOPNA, 3810-193 Aveiro, Portugal;

    Haldor Topsoe A/S, Nymollevej 55, 2800 Lyngby, Denmark;

    Haldor Topsoe A/S, Nymollevej 55, 2800 Lyngby, Denmark;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    viscosity index; lubricant; NMR;

    机译:粘度指数润滑剂核磁共振;

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