Direct synthesis of iso-paraffins from syngas with slurry phase reaction

Xiaohong Li; Xiaolei Feng; Qingjie Ge; Kaoru Fujimoto

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Direct synthesis of iso-paraffins from syngas with slurry phase reaction

机译：浆态反应从合成气直接合成异链烷烃

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The direct synthesis of gasoline-range iso-paraffins from synthesis gas (CO + H_2, syngas) via modified Fischer-Tropsch (FT) reaction was investigated in the slurry phase reaction system, the contact state of hybrid catalyst components and the composition of hybrid cat-alyst were optimized in this reaction system. The results show that the FT reaction and the in situ hydroconversion of its products occurred over hybrid catalysts containing Co/SiO_2, very high selectivity of gasoline-range iso-paraffins could be achieved.

机译：在淤浆相反应体系中，研究了通过改进的费-托反应从合成气（CO + H_2，合成气）直接合成汽油范围的异链烷烃，杂化催化剂组分的接触状态以及杂化的组成在该反应系统中优化了催化剂。结果表明，在含有Co / SiO_2的杂化催化剂上发生了FT反应及其产物的原位加氢转化，可以实现很高的汽油范围异链烷烃选择性。

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来源
《Fuel》 |2008年第5期|p.534-538|共5页
作者
Xiaohong Li; Xiaolei Feng; Qingjie Ge; Kaoru Fujimoto;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类燃料化学工业（总论）;热力工程、热机;
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2. The Role of Steric Effects and Acidity in the Direct Synthesis of iso-Paraffins from Syngas on Cobalt Zeolite Catalysts [J] . ChemCatChem . 2016,第2期

机译：空间效应和酸度在钴沸石催化剂上与合成气直接合成的ISO-链烷烃的作用
3. DME Direct Synthesis from Syngas in a Large-Scale Three-Phase Slurry Bubble Column Reactor: Transient Modeling [J] . SADEGH PAPARI, MOHAMMAD KAZEMEINI, MOSLEM FATTAHI Chemical Engineering Communications . 2014,第4a6期

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4. Direct synthesis of iso-paraffins from syngas with slurry phase reaction [C] . Xiaohong Li, Xiaolei Feng, Kaoru Fujimoto China-Japan Symposium on Coal and C1 Chemistry; 20061022-28; Chengdu(CN) . 2006

机译：浆态反应从合成气直接合成异链烷烃
5. STUDIES IN ORGANOSULFUR CHEMISTRY. I. NUCLEAR MAGNETIC RESONANCE (PROTON, CARBON-13, OXYGEN-17 (1) J(C-H)) INVESTIGATIONS OF ORGANOSULFUR COMPOUNDS. II. MECHANISTIC STUDY OF PHASE TRANSFER CATALYZED REACTIONS OF DICHLOROCARBENE WITH SULFIDES AND SULFOXIDES. III. STUDIES DIRECTED TOWARD ASYMMETRIC SYNTHESIS USING CHIRAL PHASE TRANSFER CATALYSTS. [D] . DYER, JOHN COLLINS. 1980

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6. Design of a core–shell catalyst: an effective strategy for suppressing side reactions in syngas for direct selective conversion to light olefins [O] . Li Tan, Fan Wang, Peipei Zhang, 2020

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7. Syngas conversion on calcined Fe-Ti-Zn-K catalysts. Part 2. Direct conversion of synthesis gas to light olefins in the slurry phase. [O] . Kiyomi OKABE, Tsuneji SANO, Kenji SAITOH, 1985

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8. An Investigation Directed Toward the Synthesis of Cyclic Polyphenylenes; the Chemistry of 1,3,5-Hexatriene and Its Derivatives; and Reactions of Amines in the Vapor Phase over Alumina [R] . Woods, G. F. 1965

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Direct synthesis of iso-paraffins from syngas with slurry phase reaction

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