Deep hydrodesulfurization of diesel oils. Matrix effect in the analysis of low sulfur diesel oils by energy dispersive X-ray fluorescence spectroscopy

S. Pessayre; R. Bacaud; C. Geantet

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Deep hydrodesulfurization of diesel oils. Matrix effect in the analysis of low sulfur diesel oils by energy dispersive X-ray fluorescence spectroscopy

机译：柴油的深度加氢脱硫。能量色散X射线荧光光谱法分析低硫柴油中的基质效应

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摘要

Energy dispersive X-ray fluorescence spectroscopy is the preferred method for sulfur determination in fuels. However, it has not been evaluated below 100 ppm S (w/w). In order to assess its potential for the analysis of low sulfur diesel oils, an evaluation of reproducibility and repeatability was performed and the influence of C/H ratio was evaluated. Although matrix effects originating from variation in the C/H ratio of the sample are compensated in modern instruments, this compensation may produce some systematic deviation of measured concentration.

机译：能量色散X射线荧光光谱法是确定燃料中硫的首选方法。但是，尚未评估其低于100 ppm S（w / w）的水平。为了评估其用于分析低硫柴油的潜力，进行了重现性和可重复性评估，并评估了C / H比的影响。尽管在现代仪器中可以补偿源自样品C / H比变化的基质效应，但这种补偿可能会导致测量浓度产生一些系统性偏差。

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来源
《Fuel》 |1999年第7期|p.857-860|共4页
作者
S. Pessayre; R. Bacaud; C. Geantet;
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作者单位

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类燃料化学工业（总论）;热力工程、热机;
关键词
Sulfur; X-ray fluorescence; Diesel oil;

机译：硫;X射线荧光;柴油;

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专利

1. DETERMINATION OF ORGANIC SULFUR COMPOUNDS DURING DEEP HYDRODESULFURIZATION OF DIESEL FOR ULTRA-LOW SULFUR FUEL [J] . Changlong Yin, Yongqiang Xu, Chenguang Liu Preprints . 2006,第1期

机译：超低硫燃料柴油深度加氢脱硫过程中有机硫化合物的测定
2. Quality Evaluation and Suitability Study regarding Use of Ultra Low Sulfur Diesel Fuel (ULSD) produced by Ultra Deep Hydrodesulfurization [J] . Shiro AIZAWA 日本エネルギ-学会誌 . 2003,第6期

机译：关于使用超深度加氢脱硫生产的超低硫柴油的质量评估和适用性研究
3. Principal component analysis-assisted energy dispersive X-ray fluorescence spectroscopy for non-invasive quality assurance characterization of complex matrix materials [J] . Angeyo K.H., Gari S., Mangala J.M., X-Ray Spectrometry: An International Journal . 2012,第5期

机译：主成分分析辅助能量色散X射线荧光光谱法用于复杂基质材料的无创质量保证表征
4. Online Analysis of Sulfur in Diesel line by a Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry [C] . Eduardo Perez-Careta, Juan Antonio Lopez-Ramirez, Gilberto Reynoso-Whitaker, Seventh symposium optics in industry . 2009

机译：单色波长色散X射线荧光光谱在线分析柴油中的硫
5. MCM-41-supported cobalt-molybdenum catalysts for deep hydrodesulfurization of diesel and jet fuel feedstocks. [D] . Turaga, Uday Tsrpr. 2002

机译：MCM-41负载的钴钼催化剂可用于柴油和喷气燃料原料的深度加氢脱硫。
6. Acetone Prospect as an Additive to Allow the Use of Castor and Sunflower Oils as Drop-In Biofuels in Diesel/Acetone/Vegetable Oil Triple Blends for Application in Diesel Engines [O] . Laura Aguado-Deblas, Jesus Hidalgo-Carrillo, Felipa M. Bautista, 2020

机译：丙酮展望作为添加剂以允许在柴油机/丙酮/植物油三重混合中使用蓖麻油和向日葵作为柴油中的生物燃料用于柴油发动机的应用
7. Nondestructive Characterization of Municipal-Solid-Waste-Contaminated Surface Soil by Energy-Dispersive X-ray Fluorescence and Low-Z (Atomic Number) Particle Electron Probe X-ray Microanalysis [O] . Dhrubajyoti Gupta, Rita Ghosh, Ajoy K. Mitra, 2011

机译：通过能量分散X射线荧光和低Z（原子数）粒子电子探针X射线微分分析的城市固体废物污染表面土壤的无损表征
8. Analysis of Sulfur in Fuel Oils by Energy Dispersive X-Ray Fluorescence. [R] . trovato, e. r. barron, j. w. 1979

机译：能量色散X射线荧光光谱法分析燃料油中的硫。

Deep hydrodesulfurization of diesel oils. Matrix effect in the analysis of low sulfur diesel oils by energy dispersive X-ray fluorescence spectroscopy

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