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Thermal characterization of mustard straw and stalk in nitrogen at different heating rates

机译:不同加热速率下氮芥菜秸秆和秸秆的热特性

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摘要

The pyrolysis of mustard straw and stalk was investigated at different heating rates from the ambient temperature to a temperature of 700℃ in a dynamic nitrogen flow of 40 cc/min. The thermogravimetric (TG) and derivative thermogravimetric analysis (DTG) profiles were examined for the entire degradation zone to determine the order of reaction, pre-exponential factor and activation energy. The orders of reaction were in the range of 0.61-1.02, activation energy in the range of 10.83-21.63 kJ/mol and pre-exponential factor was in the range of 15.67-27.2 min~(-1). This study of kinetics of pyrolysis of this abundant biomass is helpful in developing the mechanism of a thermochemical conversion process.
机译:在40 cc / min的动态氮气流中,在从环境温度到700℃的不同加热速率下,研究了芥菜杆和秸秆的热解。检查整个降解区的热重(TG)和导数热重分析(DTG)曲线,以确定反应顺序,指数前因子和活化能。反应级数在0.61-1.02范围内,活化能在10.83-21.63 kJ / mol范围内,预指数因子在15.67-27.2 min〜(-1)范围内。对这种丰富的生物质进行热解动力学的研究有助于开发热化学转化过程的机理。

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