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Formation of oxygenated compounds from isooctane flames

机译:由异辛烷火焰形成含氧化合物

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The formation of three families of oxygenated compounds is studied in the case of isooctane combustion. Stoichiometric, lean and rich conditions are studied at different distances from a flat burner. Nine carbonyl compounds, five alcohols and three organic acids are found in detectable concentrations in the combustion products. These oxygenated compounds are formed very quickly, their concentrations increase or remain constant for about 2-3 mm and then they fall to zero. Generally, in accordance with the results of a spark ignition engine, the oxygenated compounds have a maximum concentration at stoichiometry or under lean conditions. Some combustion products are well correlated, indicating that they are formed in parallel, or one is the precursor of the other.
机译:在异辛烷燃烧的情况下,研究了三族含氧化合物的形成。在距平板燃烧器不同距离的地方研究了化学计量的,稀薄的和浓稠的条件。在燃烧产物中发现了九种羰基化合物,五种醇和三种有机酸。这些含氧化合物的形成非常快,它们的浓度增加或保持恒定约2-3 mm,然后降至零。通常,根据火花点火发动机的结果,含氧化合物在化学计量比或稀薄条件下具有最大浓度。一些燃烧产物具有良好的相关性,表明它们是平行形成的,或者一个是另一个的先驱。

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