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The combustion of kerosene: Experimental results and kinetic modelling using 1- to 3-component surrogate model fuels

机译：煤油燃烧：使用1至3组分替代模型燃料的实验结果和动力学模型

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The oxidation of kerosene Jet-Al and that of n-decane have been studied experimentally in a jet-stirred reactor at atmospheric pressure constant residence time, over the high temperature range 900-1300 K, and for variable equivalence ratio (0.5<=PHI<=2). Concentration profile the reactants, stable intermediates, and final products have been obtained by probe sampling followed by on-line and off-line GC analyses, oxidation of neat n-decane and of kerosene in these conditions was modeled using a detailed kinetic reaction mechanism (209 species and 1 reactions, most of them reversible). The present model was successfully used to simulate the structure of a fuel-rich premixed n-decane-oxygen nitrogen flame. In the modelling, kerosene was represented by four surrogate model fuels: 100 percent 72-decane, n-decane-n-propylbenzene (74 percent /* mol), n-decane-n-propylcyclohexane (74 percent /26 percent mol), and n-decane-n-propylbenzene-n-propylcyclohexane (74 percent /15 percent /11 percent mol). The component model fuel was the most appropriate for simulating the JSR experiments. It was also successfully used to simulate the structure fuel-rich premixed kerosene-oxygen-nitrogen flame.
机译：已在大气压恒定停留时间，900-1300 K的高温范围内以及等当量比可变的情况下（0.5 <= PHI），在大气压恒定停留时间下，通过实验研究了煤油Jet-Al和正癸烷的氧化。 <= 2）。通过探针取样，在线和离线GC分析获得反应物，稳定的中间体和最终产物的浓度曲线，使用详细的动力学反应机理对在这些条件下纯正癸烷和煤油的氧化进行建模（ 209种和1种反应，其中大多数是可逆的。该模型已成功地用于模拟富含燃料的预混合正癸烷-氧氮火焰的结构。在建模中，煤油由四种替代模型燃料代表：100％72-癸烷，正癸烷-正丙基苯（74％/ * mol），正癸烷-正丙基环己烷（74％/ 26％mol），和正癸烷-正丙基苯-正丙基环己烷（74％/ 15％/ 11％mol）。组件模型燃料最适合于模拟JSR实验。它也已成功地用于模拟富含燃料的预混合煤油-氧气-氮气火焰的结构。

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