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The influence of elevated pressure on the kinetics of evolution of selected gaseous products during coal pyrolysis

机译:煤裂解过程中高压对选定气态产物析出动力学的影响

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The paper discusses the influence of the pressure of pyrolysis on the formation kinetics of C_1 -C_3 hydrocarbons, hydrogen, CO and CO_3 during pyrolysis of three selected coals of different rank. The examinations were carried out within the pressure range of 0.1 - 10 MPa under the conditions of constant residence time of primary products in the reaction zone. It was found that the pressure of pyrolysis exerts a significant influence on the formation rate of CH_4, H_2, CO and CO_2. Also, the formal kinetic parameters of formation reactions of major gaseous products during pressure pyrolysis of the examined coals were calculated.
机译:讨论了热解压力对三种不同等级煤的热解过程中C_1 -C_3烃,氢,CO和CO_3形成动力学的影响。在初级产物在反应区中的恒定停留时间的条件下,在0.1-10MPa的压力范围内进行检查。结果表明,热解压力对CH_4,H_2,CO和CO_2的生成速率有重要影响。同样,计算了被测煤在压力热解过程中主要气态产物形成反应的形式动力学参数。

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