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Fullerene blacks and cathode deposits derived from plasma arcing of graphite with naphthalene

机译:石墨与萘的等离子弧产生的富勒烯黑和阴极沉积物

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Fullerene black and cathode deposits formed by arcing graphite with naphthalene have been examined. Micro-Raman, transmission electron microscopy and differential thermal analysis show that fullerene blacks produced in the presence of naphthalene are more graphite like than those prepared in its absence. These techniques also show that the cathode deposits are altered by the presence of naphthalene in the feed material. The mixture of nanotubes so formed has a larger average void size than that formed in the absence of naphthalene. The results support proposed mechanisms of nanotube formation that involve growth by incorporation of carbon atoms into open tubes. They also show that naphthalene can be directly incorporated into fullerene black and thereby increase the number of hexagonal sheet structures in the carbon deposit.
机译:已经研究了通过将石墨与萘电弧放电而形成的富勒烯黑和阴极沉积物。显微拉曼,透射电子显微镜和差示热分析表明,与在不存在萘的情况下制备的富勒烯黑相比,在存在萘的情况下所生产的富勒烯黑更像石墨。这些技术还表明,在进料中存在萘会改变阴极沉积物。这样形成的纳米管混合物的平均空隙尺寸比不存在萘时形成的平均空隙尺寸大。结果支持拟议的纳米管形成机制,该机制涉及通过将碳原子结合到开放管中进行生长。他们还表明,萘可以直接掺入富勒烯黑中,从而增加碳沉积物中六角形片状结构的数量。

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