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首页> 外文期刊>Fuel >Characterization of iron-bearing minerals in Giril lignite from Rajasthan and study of their decomposition during combustion using 57~Fe Mossbauer Spectroscopy
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Characterization of iron-bearing minerals in Giril lignite from Rajasthan and study of their decomposition during combustion using 57~Fe Mossbauer Spectroscopy

机译:拉贾斯坦邦吉里尔褐煤中含铁矿物质的特征及其在燃烧过程中使用57〜Fe Mossbauer光谱的分解研究

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摘要

57~Fe Mossbauer spectroscopy has been used to characterize the iron-bearing minerals in the lignites from a recently discovered deposit in Giril, Rajasthan (026deg.03'N longitude and 07l 15'N latitude). An interesting feature of these lignites is the large amount of jarosite observed which is likely to have volcanic origin. Pyrite is the other iron-bearing mineral observed. The decomposition of these minerals on combustion is studied by Mossbauer experiments on samples heated at different temperatures. The decomposition route is significantly different from those normally found in coal samples. Early rupture of the polymer matrix and repulsion of hydrogen seems to have a major role in deciding the decomposition route.
机译:57-Fe Mossbauer光谱已被用来表征拉贾斯坦邦吉里尔(经度为北经026deg.03'N和北纬07l 15'N)最近发现的褐煤中的含铁矿物。这些褐煤的一个有趣特征是观察到大量的黄钾铁矾,这很可能具有火山起源。黄铁矿是观察到的另一种含铁矿物。通过燃烧在不同温度下进行的样品的Mossbauer实验研究了这些矿物在燃烧时的分解。分解途径与通常在煤样品中发现的分解途径有很大不同。聚合物基体的早期破裂和氢的排斥似乎在决定分解途径中起主要作用。

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