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Sub-continental-scale geochemical mapping: sampling, quality control and data analysis issues

机译:次大陆规模的地球化学测绘:采样,质量控制和数据分析问题

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摘要

During 1996/97, c. 1500 samples of agricultural soils from ten northern European countries (western Belarus, Estonia, Finland, northern Germany, Latvia, Lithuania, Norway, Poland, northwestern Russia and Sweden) were collected from the Ap and B/C-horizons at 750 sites. The sample sites were evenly spread over a 1 800 000 km2 area, giving an average sample density of one site per 2500 km2. The <2 mm fractions (Poland: <1 mm) of all samples were analysed for up to 62 chemical elements following ammonium acetate, aqua regia and HF extractions, and for total element concentrations by X-ray fluorescence spectrometry. Electrical conductivity, pH (water extraction) and loss on ignition (1030°C) were also determined. Each method was applied to all the samples in one laboratory only.
机译:在1996/97年度,c。来自十个 北欧国家(白俄罗斯西部,爱沙尼亚,芬兰, 北德国,拉脱维亚,立陶宛,挪威,波兰,西北 俄罗斯和瑞典)是从750个站点的A p 和B / C地平线 收集的。样本位置均匀分布在1800 000 km 2 区域,平均样本密度为每 2500 km 2 。在乙酸铵,王水和HF萃取后,分析所有样品 的<2 mm分数(波兰:<1 mm)多达62种化学元素,并进行总萃取X射线荧光光谱法测定元素 的浓度。还确定了电导率,pH(水萃取)和灼烧失重(1030°C) 。每种方法仅在一个实验室中应用于所有样品

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