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Comparing Natural Source Zone Depletion Pathways at a Fuel Release Site

机译:比较燃料释放场的自然源区枯竭途径

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摘要

Natural source zone depletion (NSZD) refers to processes within chemically impacted vadose and saturated zones that reduce the mass of contaminants remaining in a defined source control volume. Studies of large petroleum hydrocarbon release sites have shown that the depletion rate by vapor phase migration of degradation products from the source control volume through the vadose zone (V-NSZD) is often considerably higher than the rate of depletion from the source control volume by groundwater flow carrying dissolved petroleum hydrocarbons arising from dissolution, desorption, or back diffusion, and degradation products arising from biodegradation (GW-NSZD). In this study, we quantified vadose zone and GW-NSZD at a small unpaved fuel release site in California typical of those in settings with predominantly low permeability media. We estimated vadose zone using a dense network of efflux monitoring locations at four sampling events over 2 years, and GW-NSZD using groundwater monitoring data downgradient of the source control volume in three depth intervals spanning up to 9 years. On average, vadose zone was 17 times greater than GW-NSZD during the time interval of comparison, and vadose zone was in the range of rates quantified at other sites with petroleum hydrocarbon releases. Estimating vadose zone and GW-NSZD rates is challenging but the vadose zone rate is the best indicator of overall source mass depletion, whereas GW-NSZD rates may be useful as baselines to quantify progress of natural or engineered remediation in portions of the saturated zone in which there are impediments to loss of methane and other gases to the vadose zone.
机译:天然源区耗竭(NSZD)是指在化学影响的渗流和饱和区内进行的过程,这些过程可减少定义的源控制量中残留的污染物量。大型石油烃释放场所的研究表明,降解产物从气源控制量通过渗流区(V-NSZD)的气相迁移引起的耗竭率通常远高于地下水从气源控制量中的耗竭率。由溶解,解吸或逆扩散产生的溶解石油烃的流动,以及由生物降解产生的降解产物(GW-NSZD)。在这项研究中,我们量化了加利福尼亚州一个未铺砌的小型燃料释放点的渗流带和GW-NSZD,典型情况是在那些主要采用低渗透性介质的地区。我们在2年中的四个采样事件中使用密集的外排监测位置网络估算了渗流带,并使用了地下水监测数据将源控制量在3个深度间隔内降级(长达9年)来估算GW-NSZD。平均而言,在比较的时间间隔内,渗流带是GW-NSZD的17倍,渗流带在其他具有石油烃排放位点的定量速率范围内。估算渗流带和GW-NSZD的比率具有挑战性,但是渗流带的比率是总体源物质耗竭的最好指标,而GW-NSZD的比率可能用作量化天然或工程修复部分饱和带进展的基准。这会阻碍甲烷和其他气体流向渗流区。

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  • 来源
    《Ground Water Monitoring & Remediation》 |2018年第2期|24-39|共16页
  • 作者单位

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Southwest Jiaotong Univ, Fac Geosci & Environm Engn, Chengdu, Sichuan, Peoples R China;

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Univ Calif Davis, Dept Land Air & Water Resources, Davis, CA 95616 USA;

    Chevron Energy Technol Co, San Ramon, CA 94583 USA;

    Chevron Energy Technol Co, San Ramon, CA 94583 USA;

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