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Larch-derived hierarchical nitrogen-doped carbon with echinus-like architecture for supercapacitor applications

机译:LARCH-衍生的层级氮气掺杂碳,具有超级电容器应用的诸如Echinus的架构

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摘要

Echinus-like nitrogen-doped carbon with a hierarchical porous structure was synthesized from green larch waste and urea via liquid in situ doping and high-temperature carbonization. Benefitting from a large specific surface area (649 m(2) g(-1)) and hierarchical porous structure, the nitrogen-doped carbon exhibited excellent electrochemical performance for supercapacitors. Remarkably, the echinus-like nitrogen-doped carbon achieved a high specific capacitance of 340 F g(-1) at a current density of 1 A g(-1) in 6 M KOH electrolyte as well as a good performance rate and stability (with a capacitance retention of 98% after 5000 cycles). This capacitance was almost 1.5 times higher than that of undoped carbon due to the contribution of the pseudocapacitance from the nitrogen doping. Larch sawdust is a promising carbon source for fabricating inexpensive, sustainable and high-performance supercapacitor materials.
机译:用液体原位掺杂和高温碳化从绿色落叶松废物和尿素中合成了具有等级多孔结构的Echinus的氮气碳。受益于大的比表面积(649μm(2)G(-1))和分层多孔结构,氮掺杂碳表现出优异的超级电容器的电化学性能。值得注意的是,诸如氮掺杂碳的高氧化碳,在6M KOH电解质中的电流密度为1Ag(-1)的电流密度,以及良好的性能和稳定性,实现了340 f G(-1)的高比电容(在5000次循环后的电容保留为98%)。由于氮掺杂的假偶联贡献,这种电容几乎高于未掺杂的碳的1.5倍。 Larch Sawdust是一种有前途的碳源,用于制造廉价,可持续和高性能的超级电容器材料。

著录项

  • 来源
    《Holzforschung》 |2020年第5期|529-538|共10页
  • 作者单位

    Qilu Univ Technol Shandong Acad Sci State Key Lab Biobased Mat & Green Papermaking Jinan 250353 Peoples R China|Guangxi Univ Coll Light Ind & Food Engn Guangxi Key Lab Clean Pulp & Papermaking & Pollut Nanning 530004 Peoples R China;

    Qilu Univ Technol Shandong Acad Sci State Key Lab Biobased Mat & Green Papermaking Jinan 250353 Peoples R China;

    Qilu Univ Technol Shandong Acad Sci State Key Lab Biobased Mat & Green Papermaking Jinan 250353 Peoples R China;

    Qilu Univ Technol Shandong Acad Sci State Key Lab Biobased Mat & Green Papermaking Jinan 250353 Peoples R China;

    Qilu Univ Technol Shandong Acad Sci State Key Lab Biobased Mat & Green Papermaking Jinan 250353 Peoples R China;

    Tech Univ Darmstadt Dept Mat & Earth Sci Alarich Weiss Str 2 D-64287 Darmstadt Germany;

    Qilu Univ Technol Shandong Acad Sci State Key Lab Biobased Mat & Green Papermaking Jinan 250353 Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    echinus-like carbon; larch liquefaction; liquid in situ doping; supercapacitors;

    机译:Echinus样碳;落叶松液化;液体原位掺杂;超级电容器;

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