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Structural and Magnetic Properties of MnxB100−x Alloys

机译:Mn x B 100− x 合金的结构和磁性

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摘要

MnB alloys (–60) were fabricated by arc melting technique. Structural analysis showed that alloy with MnB atomic composition has a single-phase orthorhombic FeB-type MnB structure. As-synthesized alloy has a saturation magnetization of 130 emu/g at 300 K, which is the largest value previously reported. Saturation magnetization increases rapidly from 3.5 to 130 emu/g as increases from 30 to 55. Further increase of the causes the reduction of the saturation magnetization to 50 emu/g. Magnetic properties of the MnB alloy have been also evaluated by first-principles density functional theory calculations. Electronic structure calculations were performed using full potential linearized augmented plane wave method and a spin polarized generalized gradient approximation. A magnetization per MnB unit was calculated, which corresponds to 158 emu/g at 0 K. Curie temperature () of the MnB was measured as 566 K which is in good agreement with the values reported for MnB alloy.
机译:MnB合金(–60)是通过电弧熔化技术制造的。结构分析表明,具有MnB原子组成的合金具有单相正交晶FeB型MnB结构。合成后的合金在300 K时的饱和磁化强度为130 emu / g,这是先前报道的最大值。饱和磁化强度从30增至55 emu / g,迅速从3.5增至130 emu / g。原因的进一步增加导致饱和磁化强度降低至50 emu / g。 MnB合金的磁性也已经通过第一原理密度泛函理论计算进行了评估。使用全电位线性化增强平面波方法和自旋极化广义梯度近似进行电子结构计算。计算出每个MnB单位的磁化强度,对应于0 K下158 emu / g。测得的MnB居里温度()为566 K,与报告的MnB合金值非常吻合。

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