首页> 外文期刊>Ultrasonics, Ferroelectrics and Frequency Control, IEEE Transactions on >Field-induced phase transition and relaxor character in submicrometer-structured lead-free (Bi0.5Na0.5)0.94Ba0.06TiO3 piezoceramics at the morphotropic phase boundary
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Field-induced phase transition and relaxor character in submicrometer-structured lead-free (Bi0.5Na0.5)0.94Ba0.06TiO3 piezoceramics at the morphotropic phase boundary

机译:亚微米结构无铅(Bi0.5Na0.5)0.94Ba0.06TiO3压电陶瓷在变质相边界处的场致相变和弛豫特性

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摘要

Submicrometer-structured (Bi0.5Na0.5)0.94Ba0.06TiO3 ceramics ((G) -1, d15 = (158.3 - 8.31i) pC??N-1, kt = 40.4%, kp = 26.8%, and k15 = 40.2%] and d33 (148 pC??N-1) can be compared with the reported properties for coarse-grained ceramics. Shear resonance of thickness-poled plates is observed at T = 140u000b0;C. Permittivity versus temperature curves of poled samples show relaxor character up to Ti = 230u000b0;C on heating and Ti = 210u000b0;C on cooling of the depoled samples. The phase transition from the room-temperature ferroelectric (FE) to a low-temperature non-polar at zero field (LTNPZF) phase can be observed as a sharp jump in ;5;;4;33''(T) curves or, as the degree of poling decreases, as a soft change of slope of the curves at TFELTNPZF = Td = 100u000b0;C. This dielectric anomaly is not observed on cooling of depoled samples, because the FE phase is field-induced. The observed macroscopic piezoelectric activity above Td is a consequence of the coexistence of nanoregions of the FE phase in the interval between TFE-LTNPZF and Ti.
机译:亚微米结构(Bi0.5Na0.5)0.94Ba0.06TiO3陶瓷((G)-1,d15 =(158.3-8.31i)pC ?? N-1,kt = 40.4%,kp = 26.8%,k15 =可以将40.2%]和d33(148 pC ?? N-1)与已报道的粗粒陶瓷的性能进行比较。在T = 140u000b0; C处观察到厚度极板的剪切共振; C.极化样品的介电常数与温度曲线在加热后的样品中显示出弛豫特性,直到Ti = 230u000b0; C,冷却后的Ti = 210u000b0; C;在零场下从室温铁电(FE)到低温非极性的相变(LTNPZF )相可以观察为; 5 ;; 4; 33''(T)曲线中的急剧跳跃,或者随着极化程度的降低,随着TFELTNPZF = Td = 100u000b0; C时曲线斜率的软变化而观察到。由于有限元相是场感应的,因此在冷却样品时未观察到这种介电异常,而在Td上方观察到的宏观压电活性是共晶纳米区域共存的结果。 TFE-LTNPZF和Ti之间的间隔中的FE相。

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